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A limiting current oxygen sensor with 8YSZ solid electrolyte and (8YSZ)0.9(CeO2)0.1 dense diffusion barrier
Journal of Alloys and Compounds ( IF 5.8 ) Pub Date : 2021-06-22 , DOI: 10.1016/j.jallcom.2021.160903
Yihang Dong , Zhaoyang Liu , Guoxing Qiu , Lipeng Pang , Ye Han , Shuyu Yao , Jianxu Ding , Xiangnan Wang

A series of (8YSZ)1-x(CeO2)x (0 ≤ x ≤ 0.3) materials are synthesized by co-precipitation. Both crystalline structure and electrical conductivity of material are detected. (8YSZ)1-x(CeO2)x (0 ≤ x ≤ 0.3) belongs to cubic phase and (8YSZ)0.9(CeO2)0.1 is provided with the highest electrical conductivity. Select 8YSZ as solid electrolyte and (8YSZ)0.9(CeO2)0.1 as dense diffusion barrier to prepare an oxygen sensor by Pt paste bonding method. Limiting current plateau of the sensor is observable at 2% oxygen concentration and at 720–900 °C, and logarithm of the limiting current (log IL) plays a linear relationship to 1000/T. Limiting current of the sensor is observable at 850 °C and 2–14% oxygen concentration, which is linearly related to the oxygen concentration. The limiting current of the sensor does not vary significantly in the range of water vapor pressure (p(H2O)) 280.66–2268.63 Pa and in the range of carbon dioxide concentration 0–90%, respectively. The limiting current of the sensor does not decay in the oxygen concentration of 2% at 850 °C during the detection time of 120 h.



中文翻译:

具有 8YSZ 固体电解质和 (8YSZ) 0.9 (CeO 2 ) 0.1致密扩散势垒的极限电流氧传感器

 通过共沉淀合成了一系列 (8YSZ) 1- x (CeO 2 ) x (0 ≤  x ≤ 0.3) 材料。检测材料的晶体结构和电导率。(8YSZ) 1- x (CeO 2 ) x (0 ≤  x  ≤ 0.3) 属于立方相,(8YSZ) 0.9 (CeO 2 ) 0.1具有最高的电导率。选择 8YSZ 作为固体电解质和 (8YSZ) 0.9 (CeO 2 ) 0.1作为致密的扩散屏障,通过 Pt 膏键合法制备氧传感器。在2%氧气浓度和720-900°C下可观察到传感器的极限电流平台,极限电流的对数(log I L )与1000 / T呈线性关系。在 850°C 和 2-14% 的氧气浓度下可观察到传感器的极限电流,该电流与氧气浓度呈线性关系。传感器的极限电流在水蒸气压力范围内变化不大(p (H 2O)) 280.66-2268.63 Pa 和二氧化碳浓度范围分别为 0-90%。在120 h的检测时间内,传感器的极限电流在850°C下氧气浓度为2%时不衰减。

更新日期:2021-07-04
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