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Nitric acid-modified hydrochar enhance Cd2+ sorption capacity and reduce the Cd2+ accumulation in rice
Chemosphere ( IF 8.8 ) Pub Date : 2021-06-21 , DOI: 10.1016/j.chemosphere.2021.131261
Xuebo Zheng 1 , Xiaogang Ma 2 , Yun Hua 3 , Detian Li 4 , Jian Xiang 5 , Wenjing Song 1 , Jianxin Dong 1
Affiliation  

Remediating the agricultural soil polluted by cadmium (Cd) is a serious issue in China. Hydrochar showed its potential to purify Cd-contaminated water and improve Cd-contaminated soil due to its vast amounts of macro- and microporous structures. In this study, three concentration gradients of nitric acid (HNO3, mass fraction: 5%, 10%, 15%) were implemented to age pristine wheat straw hydrochar (N0-HC) aiming to improve surface physiochemical properties. Four HNO3-aging hydrochars named N0-HC, N5-HC, N10-HC, N15-HC were used to both remove Cd2+ from aqueous solution and improve soil properties. Results showed that HNO3-aging significantly improved the Cd2+ adsorption capacity by 1.9–9.9 folds compared to crude hydrochar due to the increased specific surface area (by 1.5–6.5 folds) and oxygen-containing functional group abundance (by 4.5–22.1%). Besides, initial solution pH of 8 or environmental temperature of 318.15 K performed the best Cd2+ adsorption capacity. Furthermore, the process of Cd2+ adsorption was fitted best to pseudo-second-order (R2 = 0.95) and Langmuir models (R2 = 0.98), respectively. Nanjing 46 (Oryza sativa L) and HNO3-aging hydrochars were furtherly applied into Cd-contaminated paddy soil to investigate the mitigation of Cd translation from soil to rice. N15-HC-1% (w/w) performed the best effect on reducing cadmium accumulation in various parts of rice plants. Overall, this research provided an approach to improve hydrochar capacity to remove Cd2+ from aqueous solution and mitigate Cd translation from soil to rice.

更新日期:2021-06-25
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