A review of halide charge carriers for rocking-chair and dual-ion batteries,Carbon Energy

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A review of halide charge carriers for rocking-chair and dual-ion batteries
Carbon Energy ( IF 19.5 ) Pub Date : 2021-5-7 , DOI: 10.1002/cey2.110
Sean K. Sandstrom ₁ , Xin Chen ₁ , Xiulei Ji ₁

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The study of halide species as charge carriers has emerged in recent years as an interesting alternative to the more traditional cation shuttles. Halide ion species have been explored as charge carriers for a variety of battery operation mechanisms, including anion rocking-chair batteries (i.e., halide ion batteries) and (reverse) dual-ion batteries. Here, we present a summary and analysis of how single halide ions (i.e., F? and Cl?) and metal¨Chalide complex ions (i.e., metal-based superhalides) have been used as charge carriers in rechargeable battery systems. A roadmap of future research directions is also provided to help encourage and guide researchers in making new advances in this exciting and burgeoning field.

中文翻译：

摇椅和双离子电池卤化物电荷载体综述

近年来，作为电荷载体的卤化物物种的研究已经成为更传统的阳离子穿梭的有趣替代品。已经探索了卤化物离子种类作为各种电池操作机制的电荷载体，包括阴离子摇椅电池（即卤化物离子电池）和（反向）双离子电池。在这里，我们总结和分析了单个卤化物离子（即 F2 和 Cl2）和金属-卤化物复合离子（即金属基超卤化物）如何在可充电电池系统中用作电荷载体。还提供了未来研究方向的路线图，以帮助鼓励和指导研究人员在这个令人兴奋和蓬勃发展的领域取得新进展。

更新日期：2021-09-09

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