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Evaluation of the optical properties of various-shaped and core-shell-structured lanthanum hexaboride nanoparticles based on discrete dipole approximation
Journal of Quantitative Spectroscopy and Radiative Transfer ( IF 2.3 ) Pub Date : 2021-06-20 , DOI: 10.1016/j.jqsrt.2021.107806
Luomeng Chao , Changwei Sun , Qunwei Shu , Jia Liu , Lihua Xiao

The extinction behavior of various-shaped and core-shell-structured lanthanum hexaboride (LaB6) nanoparticles was theoretically studied based on the discrete dipole approximation method. It was found that different nanoparticle shapes yielded a great influence on extinction efficiency. In comparison to spherical and cubic particles, the near-infrared (NIR) extinction peak of rod-like nanoparticles appeared at a longer wavelength. For core-shell-structured LaB6 particles, all of LaB6@TiO2, LaB6@ZnO, and LaB6@SiO2 exhibited low extinction in the visible region and high extinction in the NIR region, indicating that these three structures are potential transparent heat-shielding materials. Moreover, LaB6@TiO2 manifested better NIR extinction behavior than LaB6@ZnO and LaB6@SiO2; however, its transmittance in the visible region was slightly reduced.



中文翻译:

基于离散偶极近似的各种形状和核壳结构六硼化镧纳米粒子的光学性能评价

基于离散偶极子近似方法,从理论上研究了各种形状和核壳结构的六硼化镧(LaB 6)纳米粒子的消光行为。发现不同的纳米颗粒形状对消光效率产生很大影响。与球形和立方体颗粒相比,棒状纳米颗粒的近红外 (NIR) 消光峰出现在更长的波长处。对于核壳结构的LaB 6颗粒,所有的LaB 6 @TiO 2、LaB 6 @ZnO 和LaB 6 @SiO 2在可见光区表现出低消光,在近红外区表现出高消光,表明这三种结构是潜在的透明隔热材料。此外,LaB 6 @TiO 2表现出比LaB 6 @ZnO和LaB 6 @SiO 2更好的NIR消光行为;然而,它在可见光区的透射率略有降低。

更新日期:2021-07-02
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