Supramolecular nanostructured thiophene based materials with optoelectronic functions are of wide current interest and are playing a crucial role in different fields of nanoscience and nanotechnology. This short review gives a concise report of some particularly interesting examples from our own work concerning thiophene-based supramolecular architectures at multiple length scales, their function and application in devices. We start with some general considerations on the great chemical diversity of thiophene derivatives and their supramolecular architectures. Then we focus on how the supramolecular organization of specific thiophene derivatives may generate nanostructures that enable new functions and applications in devices. For each example, we report the synthesis of the corresponding thiophene derivatives.

1. Introduction

2. Supramolecular Organization may Impart New Functions to the System

3. Supramolecular and Optoelectronic Properties of Oligothiophene-S,S-dioxides

4. Colloidal Nanoparticles formed by Self-Assembly of Thiophene-Based Polymers

5. Conclusions and Outlook

具有光电功能的超分子纳米结构噻吩基材料具有广泛的当前兴趣，并在纳米科学和纳米技术的不同领域发挥着至关重要的作用。这篇简短的评论简要报告了我们自己的工作中一些特别有趣的例子，这些例子涉及多长度尺度的基于噻吩的超分子结构，它们的功能和在设备中的应用。我们首先对噻吩衍生物的巨大化学多样性及其超分子结构进行一些一般性考虑。然后我们关注特定噻吩衍生物的超分子组织如何产生纳米结构，从而在设备中实现新功能和应用。对于每个例子，我们报告了相应噻吩衍生物的合成。

一、简介

2. 超分子组织可能赋予系统新的功能

3. 低聚噻吩-S,S-二氧化物的超分子和光电特性

4. 噻吩基聚合物自组装形成的胶体纳米粒子

5. 结论与展望