Photoredox catalysis has received great attention in both academia and industry and remarkable progress has been made over the past decade. Now, it has been shown that a visible-light-mediated oxidative C–C bond cleavage of geminal diazides can be induced by organic dye catalysis for the synthesis of oxamates. A mechanistic study, confirmed by control experiments, indicates that this proceeds through single-electron transfer (SET). This methodology can be applied to convert a wide array of geminal diazides into oxamates.

中文翻译：

---

Geminal Diazides 的可见光介导光催化氧化 C-C 键裂解：一种草酸盐的制备方法

光氧化还原催化在学术界和工业界都受到了极大的关注，并且在过去十年中取得了显着进展。现在，已经表明，有机染料催化合成草酸盐可以诱导可见光介导的双叠氮化物氧化 C-C 键断裂。由对照实验证实的机械研究表明，这是通过单电子转移 (SET) 进行的。这种方法可用于将多种双叠氮化物转化为草酸盐。