Abstract

Two novel compounds [Zn(bitmb)(L)]·2H₂O and [Co(bitmb)(L)]·2H₂O are prepared under hydrothermal conditions (bitmb = 1,3-bis(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene; H₂L = 1,3-bis-(4-carboxy-phenoxy)propane) and characterized by the single crystal X-ray diffraction analysis. Both complexes are isostructural and contain 3-fold right-handed helical 1D chains. IR and PXRD spectra, TG curves, and photoluminescent properties are also studied.

中文翻译：

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具有三重右手螺旋链的两种 Zn(II) 和 Co(II) 配位聚合物：合成、结构表征和光致发光性能

摘要

在水热条件下制备了两种新型化合物[Zn(bitmb)(L)]·2H ₂ O和[Co(bitmb)(L)]·2H ₂ O(bitmb = 1,3-双(咪唑-1-基甲基) -2,4,6-三甲苯；H ₂ L = 1,3-双-（4-羧基-苯氧基）丙烷）并通过单晶 X 射线衍射分析表征。两种复合物都是同构的，包含 3 重右手螺旋一维链。还研究了 IR 和 PXRD 光谱、TG 曲线和光致发光特性。