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Combining SnO2-x and g-C3N4 nanosheets toward S-scheme heterojunction for high selectivity into green products of NO degradation reaction under visible light
Journal of Materiomics ( IF 8.4 ) Pub Date : 2021-06-17 , DOI: 10.1016/j.jmat.2021.06.006
Pham Van Viet , Thanh-Dat Nguyen , Dai-Phat Bui , Cao Minh Thi

NOx emissions cause many negative impacts on the living environment. The photocatalysis of semiconductors is superior for nitric oxide (NO) degradation due to their low redox potential. In this report, we combine SnO2-x/g-C3N4 heterojunction photocatalyst toward the high selectivity into green products under visible light illumination. Results show that SnO2-x/g-C3N4 heterojunction degraded 40.8% of NO, which is 1.6 times higher than that of g-C3N4. In addition, the selectivity coefficient of SnO2-x/g-C3N4 is higher 3 times than both pure SnO2-x and g-C3N4. Furthermore, SnO2-x/g-C3N4 expresses a superior stability for NO photocatalytic-degradation after five cycles. The scavenger trapping test results, and electron spin resonance (ESR) analysis also provide more understanding of the charge transfer mechanism of materials. SnO2-x/g-C3N4 heterojunction shows a high removal efficiency of NO gas, making it an up-and-coming environmental treatment candidate.



中文翻译:

将 SnO2-x 和 g-C3N4 纳米片结合到 S 型异质结,在可见光下高选择性地生成 NO 降解反应的绿色产物

NO x排放对生活环境造成许多负面影响。由于其低氧化还原电位,半导体的光催化对于一氧化氮 (NO) 的降解具有优越性。在本报告中,我们将 SnO 2-x /gC 3 N 4异质结光催化剂在可见光照射下以高选择性转化为绿色产品。结果表明,SnO 2-x /gC 3 N 4异质结降解40.8%的NO,是gC 3 N 4 的1.6倍。此外,SnO 2-x /gC 3 N 4的选择性系数比纯 SnO 2-x和 gC 3 N 4高 3 倍。此外,SnO 2-x /gC 3 N 4在五次循环后表现出优异的NO光催化降解稳定性。清道夫捕获测试结果和电子自旋共振 (ESR) 分析也提供了对材料电荷转移机制的更多理解。SnO 2-x /gC 3 N 4异质结显示出对NO气体的高去除效率,使其成为一种有前途的环境处理候选物。

更新日期:2021-06-17
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