Recent advances in the rhodium-catalyzed cyanation reactions,Applied Organometallic Chemistry

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Recent advances in the rhodium-catalyzed cyanation reactions
Applied Organometallic Chemistry ( IF 3.7 ) Pub Date : 2021-06-16 , DOI: 10.1002/aoc.6340
Puthukudichola Krishna Soumya ₁ , Thottuvazhiyil Balakrishnan Vaishak ₁ , Salim Saranya ₁ , Gopinathan Anilkumar _{1,

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Affiliation

Cyanation reactions have found a dominant position in organic synthesis due to the propensity of the cyanide group for conversion to various other functionalities. This property has opened up wide application for cyanide group. In recent years, transition metal-catalyzed reactions in general and rhodium-catalyzed reactions in particular have attracted the attention of organic chemists, which lead up to a number of cyanation procedures and synthetic transformation of the cyanide group into highly functionalized products. This review provides an overview of the rhodium-catalyzed cyanation reactions and subsequent transformations leading to the formation of various types of compounds such as amines, acids, indoles, isocyanides, nitriles, and oximes.

中文翻译：

铑催化氰化反应的最新进展

由于氰化物基团倾向于转化为各种其他官能团，因此氰化反应在有机合成中占据主导地位。这一特性为氰化物基团开辟了广泛的应用领域。近年来，过渡金属催化的反应，特别是铑催化的反应引起了有机化学家的关注，这导致了许多氰化过程和氰化物基团合成转化为高度官能化的产物。这篇综述概述了铑催化的氰化反应和随后的转化，导致形成各种类型的化合物，如胺、酸、吲哚、异氰化物、腈和肟。

更新日期：2021-08-17

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