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Recent developments in the reduction of unsaturated bonds by magnesium precursors
Applied Organometallic Chemistry ( IF 3.7 ) Pub Date : 2021-06-16 , DOI: 10.1002/aoc.6333 Indrani Banerjee 1 , Tarun K. Panda 1
Applied Organometallic Chemistry ( IF 3.7 ) Pub Date : 2021-06-16 , DOI: 10.1002/aoc.6333 Indrani Banerjee 1 , Tarun K. Panda 1
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Scientists have witnessed significant breakthroughs in s-block metal chemistry. Over the past few years, several applications in catalysis associated with alkaline-earth metal catalysts have been established owing to their abundance and lower cost. These catalysts have proved to be essential alternatives to transition metal catalysts. Several research groups have recognized the importance of magnesium complexes as highly active metal catalysts in the reduction of a series of unsaturated substrates for the synthesis of ubiquitous compounds necessary for industrial purposes. This minireview presents, based on studies published in the past recent years, a detailed discussion of catalytic hydroelementation on C–X (X = C, N, O, B, Si, S) multiple bonds, promoted by novel magnesium metal catalysts.
中文翻译：
镁前体还原不饱和键的最新进展
科学家们见证了s 区金属化学的重大突破。在过去的几年里，由于碱土金属催化剂丰富且成本较低，已经在与碱土金属催化剂相关的催化中建立了多种应用。这些催化剂已被证明是过渡金属催化剂的重要替代品。几个研究小组已经认识到镁配合物作为高活性金属催化剂在还原一系列不饱和底物以合成工业用途所需的无处不在的化合物方面的重要性。这篇小综述基于近年来发表的研究，详细讨论了由新型镁金属催化剂促进的 C-X（X = C、N、O、B、Si、S）多键的催化氢元素化。
更新日期：2021-08-17
中文翻译：
镁前体还原不饱和键的最新进展
科学家们见证了s 区金属化学的重大突破。在过去的几年里，由于碱土金属催化剂丰富且成本较低，已经在与碱土金属催化剂相关的催化中建立了多种应用。这些催化剂已被证明是过渡金属催化剂的重要替代品。几个研究小组已经认识到镁配合物作为高活性金属催化剂在还原一系列不饱和底物以合成工业用途所需的无处不在的化合物方面的重要性。这篇小综述基于近年来发表的研究，详细讨论了由新型镁金属催化剂促进的 C-X（X = C、N、O、B、Si、S）多键的催化氢元素化。
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