当前位置: X-MOL 学术J. Alloys Compd. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Effective improved energy storage performances of Na0.5Bi0.5TiO3-based relaxor ferroelectrics ceramics by A/B-sites co-doping
Journal of Alloys and Compounds ( IF 6.2 ) Pub Date : 2021-06-16 , DOI: 10.1016/j.jallcom.2021.160837
Xiang Zhang , Fan Yang , Weijun Miao , Zhen Su , Jinghao Zhao , Luomeng Tang , Yihao Shen , Di Hu , Yuyun Chen , Peng Li , Jinjun Liu , Zhongbin Pan

Environmental-friendly relaxation ferroelectrics are anticipated as an excellent comprehensive energy storage performance materials due to their near-zero remnant polarization and slim hysteresis loop. Here, the relaxor ferroelectrics (1-x)Na0.5Bi0.5TiO3-x(Sr0.7La0.2)(Ti0.8Sn0.2)O3 ((1-x)NBT-xSLTS) ceramics with outstanding energy storage performances are synthesized by solid-state reaction. The dielectric properties exhibit obvious frequency dispersion characteristics, and the diffusion coefficient (γ) increases from 1.62 to 1.75 with the doping of SLTS. Also, a large polarization difference (∆P = 20.08 μC/cm2) and a high breakdown strength (Eb = 280 kV/cm) are also achieved simultaneously. As a result, a high recoverable energy density Wrec (~ 2.52 J/cm3), together with a satisfactory efficiency η (~ 89.3%), are attained in 0.55NBT-0.45SLTS ceramic. Additionally, the corresponding samples also show satisfactory stability over the wide temperature range of 20–140 °C, with the variables of Wrec and η are less than 7% and 2%, respectively. More importantly, this ceramic has an ultrashort discharge time τ0.9 (53 ns) and a high current density J (721.86 A/cm2). All these results reveal that 0.55NBT-0.45SLTS ceramic is an ideal lead-free next-generation candidate material for pulsed power systems.



中文翻译:

A/B位共掺杂有效提高Na 0.5 Bi 0.5 TiO 3基弛豫铁电体陶瓷的储能性能

环境友好的弛豫铁电体由于其接近零的剩余极化和细长的磁滞回线,有望成为一种优异的综合储能性能材料。这里,具有优异储能性能的弛豫铁电体 (1- x )Na 0.5 Bi 0.5 TiO 3 - x (Sr 0.7 La 0.2 )(Ti 0.8 Sn 0.2 )O 3 ((1- x )NBT- x SLTS)陶瓷是固相反应合成。介电特性表现出明显的频率色散特性,扩散系数(γ)随着 SLTS 的掺杂从 1.62 增加到 1.75。此外,还同时实现了大极化差异 (Δ P  = 20.08 μC/cm 2 ) 和高击穿强度 ( E b = 280 kV/cm)。结果,在 0.55NBT-0.45SLTS 陶瓷中获得了高可恢复能量密度W rec (~ 2.52 J/cm 3 ),以及令人满意的效率η (~ 89.3%)。此外,相应的样品在 20–140 °C 的宽温度范围内也表现出令人满意的稳定性,变量W recη分别低于 7% 和 2%。更重要的是,这种陶瓷具有超短放电时间τ 0.9 (53 ns) 和高电流密度J (721.86 A/cm 2 )。所有这些结果表明,0.55NBT-0.45SLTS 陶瓷是脉冲电源系统的理想无铅下一代候选材料。

更新日期:2021-06-23
down
wechat
bug