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Temperature Dependence of Mineral Solubility in Water. Part 2. Alkaline and Alkaline Earth Bromides
Journal of Physical and Chemical Reference Data ( IF 4.4 ) Pub Date : 2018-03-01 , DOI: 10.1063/1.5010290
B. S. Krumgalz 1, 2
Affiliation  

Databases of alkaline and alkaline earth bromide solubilities in water at various temperatures were created using experimental data from publications over about the last two centuries. Statistical critical evaluation of the created databases was produced since there were enough independent data sources to justify such evaluation. The reliable experimental data were adequately described by polynomial expressions over various temperature ranges. Using the Pitzer approach for ionic activity and osmotic coefficients, the thermodynamic solubility products for the discussed bromide minerals have been calculated at various temperature intervals and also represented by polynomial expressions.

中文翻译:

矿物在水中溶解度的温度依赖性。第 2 部分。碱性和碱土溴化物

使用过去两个世纪以来出版物中的实验数据创建了各种温度下碱金属和碱土金属溴化物在水中的溶解度数据库。由于有足够的独立数据源来证明这种评估的合理性,因此对创建的数据库进行了统计批判性评估。可靠的实验数据通过多项式表达式在不同温度范围内得到充分描述。使用 Pitzer 方法计算离子活性和渗透系数,所讨论的溴化物矿物的热力学溶度积已在不同的温度间隔下计算出来,并由多项式表示。
更新日期:2018-03-01
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