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Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds and Ionic Liquids. Sublimation, Vaporization, and Fusion Enthalpies from 1880 to 2015. Part 2. C11–C192
Journal of Physical and Chemical Reference Data ( IF 4.4 ) Pub Date : 2017-03-01 , DOI: 10.1063/1.4970519
William Acree 1 , James S. Chickos 2
Affiliation  

The second part of this compendium concludes with a collection of phase change enthalpies of organic molecules inclusive of C11–C192 reported over the period 1880–2015. Also included are phase change enthalpies including fusion, vaporization, and sublimation enthalpies for organometallic, ionic liquids, and a few inorganic compounds. Paper I of this compendium, published separately, includes organic compounds from C1 to C10 and describes a group additivity method for evaluating solid, liquid, and gas phase heat capacities as well as temperature adjustments of phase changes. Paper II of this compendium also includes an updated version of a group additivity method for evaluating total phase change entropies which together with the fusion temperature can be useful in estimating total phase change enthalpies. Other uses include application in identifying potential substances that either form liquid or plastic crystals or exhibit additional phase changes such as undetected solid–solid transitions or behave ani...

中文翻译:

有机和有机金属化合物和离子液体的相变焓测量。1880 年至 2015 年的升华、汽化和聚变焓。第 2 部分。C11–C192

本纲要的第二部分总结了 1880 年至 2015 年期间报告的有机分子的相变焓集合,包括 C11-C192。还包括相变焓,包括有机金属、离子液体和一些无机化合物的熔化、蒸发和升华焓。该纲要的论文 I 单独出版,包括从 C1 到 C10 的有机化合物,并描述了一种用于评估固、液和气相热容以及相变温度调节的群加法方法。本纲要的论文 II 还包括用于评估总相变熵的群可加性方法的更新版本,该方法与融合温度一起可用于估计总相变焓。
更新日期:2017-03-01
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