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SO2 removal performance for the solution absorption system applied to coal-fired flue gas
Journal of the Energy Institute ( IF 5.6 ) Pub Date : 2021-06-15 , DOI: 10.1016/j.joei.2021.06.010
Hao Zhang , Yanhua Lai , Lianhong Yang , Jiyun Tang , Chang Li , Yong Dong

The solution absorption system has great potential for recovery of water and latent heat from industrial gas. However, few investigations have been conducted on the synergistic removal of SO2 and the treatment of the associated precipitation when the method is applied for flue gas from coal-fired power plants. To solve this problem, a falling-film reaction platform was established and the CaCl2 solution was chosen as the liquid desiccant. The effects of solution temperature and concentration, solution pH, O2 content and catalyst concentration on the efficiency of SO2 removal were investigated. The solubility of the CaSO4·2H2O precipitates in the CaCl2 solution was measured. The results revealed that the precipitated component was influenced by the O2 content. The decrease in solution pH was responsible for the decrease in the efficiency of SO2 removal. The highest SO2 removal efficiency of 95.6% was obtained during the operation of solution circulation in this experiment. In addition, the solubility test showed that a higher temperature, a lower concentration and the addition of Ca(OH)2 were conducive to reducing the solubility of the CaSO4·2H2O precipitate in CaCl2 solution.



中文翻译:

燃煤烟气溶液吸收系统SO 2去除性能

溶液吸收系统在回收工业气体中的水和潜热方面具有巨大潜力。然而,该方法应用于燃煤电厂烟气中SO 2协同脱除和伴生沉淀处理的研究较少。为解决这一问题,搭建了降膜反应平台,选用CaCl 2溶液作为液体干燥剂。研究了溶液温度和浓度、溶液pH、O 2含量和催化剂浓度对SO 2去除效率的影响。CaSO 4 ·2H 2 O在CaCl 2 中的溶解度溶液进行了测量。结果表明,析出组分受O 2含量的影响。溶液 pH 值的降低是 SO 2去除效率降低的原因。本实验在溶液循环操作过程中获得了最高的SO 2去除效率,达到95.6%。此外,溶解度试验表明,较高的温度、较低的浓度和Ca(OH) 2 的加入有利于降低CaSO 4 ·2H 2 O沉淀物在CaCl 2溶液中的溶解度。

更新日期:2021-06-19
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