当前位置: X-MOL 学术Polym. J. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Removal of mononuclear alkylaluminum species in aluminoxane using a crosslinked polymer bearing bulky phenoxy groups
Polymer Journal ( IF 2.3 ) Pub Date : 2021-06-14 , DOI: 10.1038/s41428-021-00507-w
Ryo Tanaka , Mari Nishizono , Yuushou Nakayama , Takeshi Shiono

In olefin polymerization using methylaluminoxane (MAO) as a cocatalyst, the remaining trialkylaluminum (R3Al) in MAO sometimes leads to negative effects, such as a decrease in activity and molecular weight of the obtained polymer. Thus, in this study, the amount of R3Al in modified MAO (MMAO) was reduced by using a crosslinked terpolymer bearing bulky phenoxy groups as a solid support for R3Al. The R3Al removal efficiency of the terpolymer at a certain hydroxy group content was found to be much higher than that of SiO2, which has been previously reported to be an efficient R3Al remover. This is probably because of the steric bulkiness around the hydroxy groups and because some R3Al is physically adsorbed into the terpolymer. The chain transfer reaction derived from residual R3Al in propylene polymerization is mostly suppressed after the treatment of MMAO with the terpolymer.



中文翻译:

使用带有庞大苯氧基的交联聚合物去除铝氧烷中的单核烷基铝物质

在使用甲基铝氧烷(MAO)作为助催化剂的烯烃聚合中,MAO中剩余的三烷基铝(R 3 Al)有时会导致负面影响,例如所得聚合物的活性和分子量降低。因此,在本研究中,通过使用带有庞大苯氧基的交联三元共聚物作为 R 3 Al的固体载体,减少了改性 MAO (MMAO)中 R 3 Al的含量。发现在特定羟基含量下,三元共聚物的 R 3 Al 去除效率远高于 SiO 2 的去除效率,SiO 2先前已被报道为有效的 R 3 Al 去除剂。这可能是因为羟基周围的空间体积大,并且因为一些 R3 Al 物理吸附到三元共聚物中。在用三元共聚物处理MMAO后,丙烯聚合中由残留的R 3 Al衍生的链转移反应大多被抑制。

更新日期:2021-06-14
down
wechat
bug