Abstract

An efficient method for the preparation of trihalomethyl (Cl, Br) ketones by the oxidation of trihalomethyl carbinols with 2-iodoxybenzoic acid in tert-butanol under heating has been developed. A series of trihalomethyl ketones have been synthesized through a simple, convenient, and environmentally friendly method with excellent yields.

中文翻译：

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使用 2-碘氧基苯甲酸从三卤甲基甲醇 (Hal = Cl, Br) 合成三卤甲基酮

摘要

开发了一种通过在叔丁醇中加热氧化三卤甲基甲醇与 2-碘氧基苯甲酸制备三卤甲基 (Cl, Br) 酮的有效方法。通过简便、环保、收率优良的方法合成了一系列三卤甲基酮。