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Supersonically sprayed transparent flexible multifunctional composites for self-cleaning, anti-icing, anti-fogging, and anti-bacterial applications
Composites Part B: Engineering ( IF 12.7 ) Pub Date : 2021-06-09 , DOI: 10.1016/j.compositesb.2021.109070
Chanwoo Park , Taegun Kim , Yong-Il Kim , Min Wook Lee , Seongpil An , Sam S. Yoon

We used supersonic aerosol deposition to fabricate transparent flexible thin “glass” films, comprising SiO2 and ZnO, with antibacterial, superhydrophilic, and anti-fog properties. A polystyrene solution, which was supersonically sprayed onto the glass film to augment the superhydrophobicity, endowed the film with self-cleaning and anti-frost characteristics. The glass films have a thickness of 2–2.5 μm with a maximum roughness of approximately 0.25 μm. The sprayed polystyrene (PS) layer (approximately 200 nm thick) decreased the transparency of the film to 80% relative to that of the pure glass film (90%) at 580 nm. The large water contact angle of 165° renders the PS-coated glass film superhydrophobic, which slows the nucleation of condensing droplets and delays the subsequent formation of ice, known as the anti-frost or anti-icing effect. The superhydrophobicity is also responsible for the self-cleaning effect of the rolling droplets over a tilted substrate. The hydrophilicity of the glass-coated film (or simply, glass film) without PS facilitated the formation of a thin liquid layer, which minimized light scattering and augmented the anti-fog effect. Finally, the bacterial inhibition rates of the glass and PS-coated glass films were 97.5% and 96.3%, respectively. These multifunctional films are expected to minimize the transmission of bacteria resulting from physical contact.



中文翻译:

用于自清洁、防冰、防雾和抗菌应用的超声喷涂透明柔性多功能复合材料

我们使用超音速气溶胶沉积来制造透明的柔性薄“玻璃”薄膜,包括 SiO 2和 ZnO,具有抗菌、超亲水和防雾特性。将聚苯乙烯溶液超声喷涂到玻璃膜上以增强超疏水性,使膜具有自清洁和防霜特性。玻璃膜的厚度为 2-2.5 μm,最大粗糙度约为 0.25 μm。相对于纯玻璃膜 (90%) 在 580 nm 处,喷涂的聚苯乙烯 (PS) 层(约 200 nm 厚)将膜的透明度降低至 80%。165°的大水接触角使涂有PS的玻璃膜具有超疏水性,这减缓了冷凝液滴的成核并延迟了随后的冰的形成,称为防霜或防冰效果。超疏水性也是导致滚动液滴在倾斜基底上产生自清洁效果的原因。不含 PS 的玻璃涂层膜(或简称为玻璃膜)的亲水性促进了薄液层的形成,从而最大限度地减少了光散射并增强了防雾效果。最后,玻璃和PS涂层玻璃膜的细菌抑制率分别为97.5%和96.3%。这些多功能薄膜有望最大限度地减少因身体接触而导致的细菌传播。分别。这些多功能薄膜有望最大限度地减少因身体接触而导致的细菌传播。分别。这些多功能薄膜有望最大限度地减少因身体接触而导致的细菌传播。

更新日期:2021-06-19
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