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Dopamine Functionalized S,N Co-doped Carbon Dots as a Fluorescent Sensor for the Selective Detection of Fe3+ and Fe2+ in Water
Analytical Sciences ( IF 1.8 ) Pub Date : 2021-06-10 , DOI: 10.2116/analsci.20p294
Siyu LEI 1, 2 , Na CHANG 1, 2 , Jimei ZHANG 1, 2 , Haitao WANG 1, 3
Affiliation  

In current work, novel functionalized carbon dots have been designed and synthesized by covalently linking dopamine to the surface of S,N co-doped carbon dots (DA-S,N-CDs) for the selective detection of Fe3+ and Fe2+ in water. The as-synthesized DA-S,N-CDs emit blue fluorescence peaked at 470 nm and exhibit excitation-dependent tunable emissions. The tolerance towards pH, salt, and UV irradiation of synthesized carbon dots reveals excellent stability. Upon exposure to Fe3+ or Fe2+, the fluorescence of DA-S,N-CDs was selectively quenched, while other competitive cations did not change significantly. Under the optimal experimental conditions, the fluorescence intensity of DA-S,N-CDs showed a good linear relationship with the concentrations of Fe3+ and Fe2+ (5 – 200 μM for Fe3+ and 5 – 300 μM for Fe2+), and the limit of detection was 2.86 and 2.06 μM, respectively. Furthermore, considering the excellent stability and anti-interference, DA-S,N-CDs have been successfully used for the detection of Fe3+ and Fe2+ in environmental water.

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中文翻译:

多巴胺功能化 S、N 共掺杂碳点作为荧光传感器,用于选择性检测水中的 Fe3+ 和 Fe2+

在目前的工作中,通过将多巴胺共价连接到 S,N 共掺杂碳点 (DA-S,N-CDs) 的表面,设计并合成了新型功能化碳点,用于选择性检测 Fe 3+和 Fe 2+在水里。合成后的 DA-S、N-CD 发出蓝色荧光,峰值为 470 nm,并表现出依赖于激发的可调发射。合成碳点对 pH、盐和紫外线照射的耐受性显示出优异的稳定性。接触 Fe 3+或 Fe 2+ 时, DA-S,N-CDs 的荧光被选择性淬灭,而其他竞争性阳离子没有显着变化。在最佳实验条件下,DA-S的荧光强度,N-CDS表明线性与Fe的浓度关系的良好3+和Fe 2+(5 - 200μM为铁3+和5 - 300μM为铁2 + ),检测限分别为 2.86 和 2.06 μM。此外,考虑到优异的稳定性和抗干扰性,DA-S,N-CDs已成功用于检测环境水中的Fe 3+和Fe 2+

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更新日期:2021-06-09
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