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Electrochemical Behavior of Vanadium Carbide in Neutral Aqueous Electrolytes
Chinese Physics Letters ( IF 3.5 ) Pub Date : 2021-06-04 , DOI: 10.1088/0256-307x/38/5/058201
Chaofan Chen 1 , Di Pang 1 , Xiaotong Wang 1 , Gang Chen 1, 2 , Fei Du 1, 2 , Yu Gao 1
Affiliation  

The V2C compound, belonging to the group of two-dimensional transition metal carbonitrides, or MXenes, has demonstrated a promising electrochemical performance in capacitor applications in acidic electrolytes; however, there is evidence to suggest that V2C is unstable in an acidic environment. On the other hand, the performance of V2C in neutral aqueous electrolytes is still moderate, and has not yet been systematically studied. The charge storage mechanism in a V2C electrode, employed in neutral aqueous electrolytes, is investigated via cyclic voltammetry testing and in situ x-ray diffraction (XRD). Good specific capacitances are achieved, specifically 208 F/g in 0.5 M Li2SO4, 225 F/g in 1 M MgSO4, 120 F/g in 1M Na2SO4, and 104 F/g in 0.5 M K2SO4. Using in situ XRD, we observe that, during the charge and discharge process, the c-lattice parameter shrinks or expands by up to 0.25 in MgSO4, and 0.29 in Li2SO4 which demonstrates the intercalation/de-intercalation of cations into the d-V2C layer.



中文翻译:

碳化钒在中性水电解质中的电化学行为

V 2 C 化合物属于二维过渡金属碳氮化物或 MXenes,在酸性电解质中的电容器应用中表现出良好的电化学性能。然而,有证据表明 V 2 C 在酸性环境中不稳定。另一方面,V 2 C 在中性水系电解质中的表现还算中等,尚未得到系统研究。通过循环伏安法测试和原位X 射线衍射 (XRD)研究了用于中性水性电解质的 V 2 C 电极中的电荷存储机制。实现了良好的比电容,特别是在 0.5 M Li 2 SO中为 208 F/g4,在 1 M MgSO 4中为 225 F/g,在 1M Na 2 SO 4中为 120 F/g,在 0.5 MK 2 SO 4中为 104 F/g 。使用原位XRD,我们观察到,在充电和放电过程中, MgSO 4中的c晶格参数收缩或膨胀高达 0.25 ,而 Li 2 SO 4中的 c 晶格参数收缩或膨胀高达 0.29,这证明了阳离子的嵌入/脱嵌。d -V 2 C 层。

更新日期:2021-06-04
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