Abstract

In the present work, poly(2-aminothiazole)/organoclay nanocomposites were synthesized via intercalative in situ oxidative polymerization of 2-aminothiazole using ammonium persulfate as an initiator. A certain kind of co-intercalation of montmorillonite was accomplished by polyhydroxy iron cation and its organophilization using cetyltrimethylammonium bromide surfactant. The objective was to evaluate the influence of the organoclays basal spacing on the structural and morphological properties of the synthesized nanocomposites. The presence of iron in nanocomposite was confirmed by XPS analysis. The resulting nanocomposites were fully characterized by FTIR spectroscopy and X-ray diffraction.

中文翻译：

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导电聚（2-氨基噻唑）/改性粘土纳米复合材料的合成与表征

摘要

在目前的工作中，使用过硫酸铵作为引发剂，通过 2-氨基噻唑的插入原位氧化聚合合成了聚（2-氨基噻唑）/有机粘土纳米复合材料。通过多羟基铁阳离子及其使用十六烷基三甲基溴化铵表面活性剂的亲有机化实现了蒙脱石的某种共嵌入。目的是评估有机粘土基础间距对合成纳米复合材料的结构和形态特性的影响。XPS 分析证实了纳米复合材料中铁的存在。所得纳米复合材料通过 FTIR 光谱和 X 射线衍射进行了充分表征。