当前位置: X-MOL 学术Mater. Renew. Sustain. Energy › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Stability, reusability, and equivalent circuit of TiO2/treated metakaolinite-based dye-sensitized solar cell: effect of illumination intensity on Voc and Isc values
Materials for Renewable and Sustainable Energy ( IF 3.6 ) Pub Date : 2021-06-03 , DOI: 10.1007/s40243-021-00195-9
Winda Rahmalia , Imelda H. Silalahi , Thamrin Usman , Jean-François Fabre , Zéphirin Mouloungui , Georges Zissis

In this research, treated metakaolinite (TMK) was introduced into the TiO2 photoelectrode to fabricated dye-sensitized solar cells (DSSCs). The photovoltaic cells have four main natural components, i.e., a photosensitizer (carotenoid bixin), photoelectrode (TiO2/kaolinite), electrolyte (glycerine carbonate derivative), and counter-electrode (carbon). Their stability, reusability, and equivalent circuit were studied. The presence of 5% of TMK in anatase TiO2 paste decreased the TiO2 band gap from 3.21 to 3.16 eV. The result showed that the presence of 5% of TMK in TiO2 paste was more favorable to obtain higher energy conversion efficiency. Under a light intensity of 200 W/m2, it produced an energy conversion yield of 0.086%. The combination of the electrolyte and the TMK demonstrated a synergistic effect to improve the electrical properties of the DSSC. The energy storage function worked well until the third day of analysis. The DSSC based on TiO2/TMK photoelectrode exhibited 16 times better stability than pure TiO2-based photoelectrode. The Faraday charge transfer processes showed that the TiO2/TMK photoelectrode is not in direct contact with the carbon counter-electrode.



中文翻译:

TiO2/处理过的偏高岭石基染料敏化太阳能电池的稳定性、可重用性和等效电路:光照强度对 Voc 和 Isc 值的影响

在这项研究中,将处理过的偏高岭石(TMK)引入到 TiO 2光电极中以制造染料敏化太阳能电池(DSSC)。光伏电池具有四种主要的天然成分,即光敏剂(类胡萝卜素联素)、光电极(TiO 2 /高岭石)、电解质(甘油碳酸酯衍生物)和反电极(碳)。研究了它们的稳定性、可重用性和等效电路。锐钛矿 TiO 2糊中 5% TMK 的存在将 TiO 2带隙从 3.21 eV降低到 3.16 eV。结果表明,在TiO 2浆料中加入5%的TMK更有利于获得更高的能量转换效率。200 W/m 2光强下,它产生了 0.086% 的能量转化率。电解质和 TMK 的组合显示出协同效应以改善 DSSC 的电性能。直到分析的第三天,能量存储功能都运行良好。基于TiO 2 /TMK 光电极的DSSC表现出比纯TiO 2基光电极高16 倍的稳定性。法拉第电荷转移过程表明,TiO 2 /TMK 光电极不与碳对电极直接接触。

更新日期:2021-06-03
down
wechat
bug