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Zirconium Doped Copper Ferrite (CuFe2O4) Nanoparticles for the Enhancement of Visible Light-Responsive Photocatalytic Degradation of Rose Bengal and Indigo Carmine Dyes
Journal of Cluster Science ( IF 2.7 ) Pub Date : 2021-06-02 , DOI: 10.1007/s10876-021-02094-5
P. Nancy Dayana , M. John Abel , P. Fermi Hilbert Inbaraj , S. Sivaranjani , R. Thiruneelakandan , J. Joseph prince

In this work, the Zr doped CuFe2O4 nanoparticles were prepared with different concentrations of zirconium ions through the chemical precipitation method. The Zr ion are added as Zr(x wt%):CuFe2(100-xwt%)O4 with (x = 0, 1, 3, 5). The crystal structure and phase were identified by XRD characterization. From the XRD the average crystallite sizes of the synthesized material were calculated and are obtained as 33 nm, 34 nm, 38 nm, and 42 nm. FT-IR characterization was taken to find the functional groups present in the material. The optical properties and corresponding optical band gap were determined by UV-DRS and PL studies. The bandgap was found to be 1.39 eV, 1.56 eV, 1.80 eV, and 1.97 eV for 0%, 1%, 3%, and 5% Zr doped CuFe2O4 nanoparticles respectively. The surface morphology is studied by SEM analysis. EDAX is used for the elemental composition analysis of the prepared materials. Further, the photocatalytic performances were studied with Rose Bengal (RB) and Indigo Carmine (IC) textile dyes. The maximum degradation percentage was obtained as 88% for RB dye and 71% for IC dye with 5wt% Zr doped CuFe2O4 nanoparticles within 120 min. The mineralization of the degraded dye solution was confirmed by the Chemical Oxygen Demand (COD) technique.



中文翻译:

锆掺杂的铜铁氧体 (CuFe2O4) 纳米颗粒用于增强玫瑰红和靛蓝胭脂红染料的可见光响应光催化降解

在这项工作中,通过化学沉淀法制备了不同浓度锆离子的 Zr 掺杂的 CuFe 2 O 4纳米粒子。Zr 离子以 Zr (x wt%) : CuFe 2(100-xwt%) O 4 的形式添加与 (x = 0, 1, 3, 5)。通过XRD表征确定晶体结构和相。从XRD计算合成材料的平均微晶尺寸并获得为33nm、34nm、38nm和42nm。进行 FT-IR 表征以发现材料中存在的官能团。光学特性和相应的光学带隙由 UV-DRS 和 PL 研究确定。发现对于 0%、1%、3% 和 5% Zr 掺杂的 CuFe 2 O 4的带隙为 1.39 eV、1.56 eV、1.80 eV 和 1.97 eV分别是纳米颗粒。通过SEM分析研究表面形态。EDAX用于制备材料的元素组成分析。此外,还研究了孟加拉 (RB) 和靛蓝 (IC) 纺织染料的光催化性能。在 120 分钟内,RB 染料的最大降解百分比为 88%,IC 染料为 71%,其中含有 5wt% Zr 掺杂的 CuFe 2 O 4纳米颗粒。降解染料溶液的矿化由化学需氧量 (COD) 技术证实。

更新日期:2021-06-02
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