MOF-on-MOF Architectures: Applications in Separation, Catalysis, and Sensing,Bulletin of the Korean Chemical Society

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MOF-on-MOF Architectures: Applications in Separation, Catalysis, and Sensing
Bulletin of the Korean Chemical Society ( IF 2.3 ) Pub Date : 2021-05-31 , DOI: 10.1002/bkcs.12335
Doo Hwan Hong ₁ , Hui Su Shim ₁ , Junsu Ha ₁ , Hoi Ri Moon ₁

Affiliation

Metal–organic frameworks (MOFs) are porous crystalline materials with a high tunability. To improve the functionality of the original frameworks, several strategies, such as the use of different metal cations and organic ligands and post-synthetic modification, have been developed, enabling the use of MOFs in numerous practical applications in various fields. Recently, another approach, i.e., MOF-on-MOF architecturing, has been actively studied by combining two or more MOFs into a composite. MOF-on-MOF materials not only possess the intrinsic properties of each MOF but also exhibit unprecedented synergism within a single system, resulting in a considerable potential for various applications. This review summarizes the interesting areas of application of MOF-on-MOF architectures into three categories: separation, catalysis, and sensing. In particular, the synergism occurring within such MOF-on-MOF architectures is discussed.

中文翻译：

MOF-on-MOF 架构：分离、催化和传感中的应用

金属有机框架（MOF）是具有高可调性的多孔晶体材料。为了改善原始框架的功能，已经开发了多种策略，例如使用不同的金属阳离子和有机配体以及合成后修饰，从而使 MOF 在各个领域的众多实际应用中得以使用。最近，另一种方法，即.，MOF-on-MOF 架构，已经通过将两个或多个 MOF 组合成一个复合材料进行了积极的研究。MOF-on-MOF 材料不仅具有每个 MOF 的固有特性，而且在单个系统内表现出前所未有的协同作用，从而在各种应用中具有相当大的潜力。本综述将 MOF-on-MOF 架构的有趣应用领域总结为三类：分离、催化和传感。特别地，讨论了这种 MOF-on-MOF 架构中发生的协同作用。

更新日期：2021-07-27

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