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Optimization of alkali fusion process for determination of I-129 in solidified radwastes by neutron activation
Applied Radiation and Isotopes ( IF 1.6 ) Pub Date : 2021-05-29 , DOI: 10.1016/j.apradiso.2021.109762
Jiunn-Hsing Chao , Chun-Yu Chuang , Wei-Chun Chou , Chun-Liang Kuo , Feng-Chih Chang , An-Chung Chiang

This study determines the optimum temperature for the alkali fusion process used to effectively separate iodine from solidified radwaste attaining low-level 129I by neutron activation. The alkali fusion temperature was adjusted to 120, 200, and 400 °C to approach the optimum conditions associated with a good statistical distribution of the measured 129I data and high chemical recovery yield. Statistical analysis revealed that the optimum temperature of the alkali fusion process was 200 °C, displaying good central tendency and low variance of the measured 129I data, and the respective chemical recovery yields were higher than other temperatures. The optimum fusion condition provides more reliable scaling factors (129I/137Cs) of radwaste.



中文翻译:

中子活化法测定固化放射性废物中I-129的碱聚变工艺优化

这项研究确定了碱聚变过程的最佳温度,该过程用于从通过中子活化获得低水平129 I 的固化放射性废物中有效分离碘。将碱熔温度调整为 120、200 和 400 °C,以接近与测得的129 I 数据的良好统计分布和高化学品回收率相关的最佳条件。统计分析表明,碱熔过程的最适温度为200 ℃,129 I实测数据显示出良好的集中趋势和低方差,各自的化学回收率均高于其他温度。最佳融合条件提供更可靠的缩放因子 ( 129 I/ 137Cs) 的放射性废物。

更新日期:2021-06-18
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