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Photoluminescence and Crystallinity of High Quality CdS1−xSex Synthesized in Ammonium Water Medium
Journal of Electronic Materials ( IF 2.2 ) Pub Date : 2021-04-28 , DOI: 10.1007/s11664-021-08953-1
Yufeng Chen , Chao Li , Xiaodan Ren , Kunlei Zhang , Li Wang

CdS1−xSex nanomaterial with high optical and structural quality has been synthesized in ammonium water via a simple hydrothermal reaction. Structural and compositional analyses suggest that the CdS1−xSex synthesized in ammonium water (NH3·H2O) medium has better crystallinity and more Se content compared with that of CdS1−xSex synthesized in sodium hydroxide (NaOH) solution medium. Photoluminescence spectra show that the CdS1−xSex synthesized in NH3·H2O solution exhibits stronger red luminescence than that of the CdS1−xSex synthesized in NaOH solution. Transmission electron microscopy confirms that the size of the CdS1−xSex synthesized in NH3·H2O solution is obviously larger than that of the CdS1−xSex synthesized in NaOH solution. Basing on these results, the mechanism of CdS1−xSex formed in NH3·H2O was compared with that of the CdS1−xSex synthesized in NaOH solution media.



中文翻译:

铵水介质中合成的高质量CdS1-xSex的光致发光和结晶度

通过简单的水热反应在铵水中合成了具有高光学和结构质量的CdS 1-x Se x纳米材料。结构和组成分析表明,与在氢氧化钠(NaOH)中合成的CdS 1-x Se x相比,在铵水(NH 3 ·H 2 O)介质中合成的CdS 1-x Se x具有更好的结晶度和更多的Se含量。溶液介质。光致发光光谱表明,在NH 3 ·H 2 O溶液中合成的CdS 1-x Se x呈现出比CdS更强的红色发光。1-x Se x在NaOH溶液中合成。透射电子显微镜证实,在NH 3 ·H 2 O溶液中合成的CdS 1-x Se x的尺寸明显大于在NaOH溶液中合成的CdS 1-x Se x的尺寸。基础上这些结果,硫化镉的机构-X 1X形成在NH 3 ·H 2 O的与CD的相比,1-XX在NaOH溶液中的媒体合成。

更新日期:2021-05-27
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