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Efficient flotation recovery of lead and zinc from refractory lead-zinc ores under low alkaline conditions
Geochemistry ( IF 2.6 ) Pub Date : 2021-05-26 , DOI: 10.1016/j.chemer.2021.125769
Qian Wei , Liuyang Dong , Wenqing Qin , Fen Jiao , Zhongxu Qi , Cheng Feng , Dayong Sun , Long Wang , Shunyuan Xiao

In this study, a new flotation approach, a low-alkaline and non-desliming process, was introduced for improving lead and zinc recoveries, lowering production cost and reducing environmental pollution. Lab-scale experiments results show that the new process contributed to the flotation of the complex mixed sulfide-oxide lead and zinc ore regarding two aspects: (1) High alkaline process (pH = 12±) was replaced by low alkaline process (pH = 9±) by using collector WS (a mixture of ethyl thiocarbamate, ammonium dibutyldithiophosphate and dithiophosphate-25) and combined depressant Na2S/ZnSO4/Na2SO3 for lead sulfide flotation; (2) Non-desliming process was successfully achieved by using collector MA (a mixture of ether amine, hydroxyethyl cellulose and polyacrylic acid) and combined depressant SHP/SS (sodium hexametaphosphate/sodium silicate) for zinc oxide flotation. And 43.37% Pb in the Pb concentrate was recovered, the corresponding Pb grade was 52.73%, total 84.42% Zn was recovered by the flotation of zinc sulfide minerals and zinc oxide minerals. Moreover, the two aspects of the new approach were systematically verified from lab-scale to industrial-scale application. The industrial-scale flotation tests show that Pb recovery in Pb concentrate increased by 1.86% compared with that of original system during industrial-scale tests period, and the Pb recovery increased by 4.09% compared with that of original system before industrial-scale tests period, while the Zn operating recovery in zinc oxide concentrate improved by 19.52%. Moreover, the total reagent cost of the whole new process significantly declined by 3.93 yuan per ton of ore.



中文翻译:

低碱性条件下从难选铅锌矿中高效浮选回收铅锌

在这项研究中,引入了一种新的浮选方法,一种低碱和非脱泥工艺,以提高铅和锌的回收率,降低生产成本并减少环境污染。实验室规模的实验结果表明,新工艺对复杂混合硫化物-氧化物铅锌矿的浮选有两个方面的贡献:(1)高碱工艺(pH = 12±)被低碱工艺(pH = 9±) 通过使用捕收剂 WS(硫代氨基甲酸乙酯、二丁基二硫代磷酸铵和二硫代磷酸-25 的混合物)和组合抑制剂 Na 2 S/ZnSO 4 /Na 2 SO 3用于硫化铅浮选;(2)采用捕收剂MA(醚胺、羟乙基纤维素和聚丙烯酸的混合物)和复合抑制剂SHP/SS(六偏磷酸钠/硅酸钠)进行氧化锌浮选,成功实现了不脱泥工艺。并通过硫化锌矿物和氧化锌矿物的浮选,回收了铅精矿中43.37%的铅,相应的铅品位为52.73%,共回收了84.42%的锌。此外,从实验室规模到工业规模应用,系统验证了新方法的两个方面。工业规模浮选试验表明,在工业规模试验期间,铅精矿的铅回收率比原系统提高了1.86%,铅回收率提高了4。与工业规模试验期前原系统相比提高了09%,氧化锌精矿的锌运行回收率提高了19.52%。而且,整个新工艺的试剂总成本每吨矿石显着下降了3.93元。

更新日期:2021-05-26
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