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Bifunctional beginnings
Nature Reviews Chemistry ( IF 38.1 ) Pub Date : 2021-05-26 , DOI: 10.1038/s41570-021-00295-0
Rosie J Somerville 1
Affiliation  

In the early 1980s, Shvo and co-workers reported a molecular ruthenium complex that was active in the catalytic dehydrogenation of alcohols and the hydrogenation of carbonyl compounds. Although the reactions themselves were already known, the ligand represented a new paradigm in bond formation/breaking processes that influences homogeneous catalysis to this day. The early 1980s witnessed the report of a molecular ruthenium complex active for dehydrogenation of alcohols and hydrogenation of carbonyl compounds. The ligand used represented a new paradigm that influences homogeneous catalysis to this day.

中文翻译:

双功能开端

在 80 年代初期,Shvo 及其同事报道了一种分子钌络合物,它在醇的催化脱氢和羰基化合物的氢化中具有活性。尽管反应本身已经为人所知,但配体代表了键形成/断裂过程的新范例,至今仍影响均相催化。80 年代初见证了对醇脱氢和羰基化合物氢化具有活性的分子钌络合物的报道。使用的配体代表了一种影响均相催化至今的新范例。
更新日期:2021-05-26
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