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Formation Mechanism of Large-size CaO–Al2O3–MgO–SiO2 Inclusions in High Carbon Chromium Bearing Steel
ISIJ International ( IF 1.6 ) Pub Date : 2021-07-15 , DOI: 10.2355/isijinternational.isijint-2020-729
Zhiqi Miao 1 , Guoguang Cheng 1 , Shijian Li 1 , Wensheng Qiu 2 , Lingyu Zeng 2 , Hu Long 2
Affiliation  

Industrial experiments and thermodynamic analyses were carried out to investigate the formation mechanism of large-size (>30 µm) CaO–Al2O3–MgO–SiO2 (CAMS) inclusions in high carbon chromium bearing steel. It was found that the large-size CAMS inclusions existed during the whole refining process, most of which compositions were located in the liquid region. The average content of SiO2 in CAMS inclusions decreased from 27.5 mass% at argon-blowing station to 3.0 mass% in the hot-rolled bars. The results calculated by Factsage 7.3 indicated that the CAMS inclusions were originated from slag entrapment. During BOF tapping, the low basicity slag with 60 mass% SiO2 was entrapped into steel and combined with the deoxidation product Al2O3, forming a large amount of liquid CAMS inclusions. During LF refining process, [Al], [Ca] and [Mg] in molten steel were affected by the activities of corresponding slag components. The reaction between these three elements and SiO2 in CAMS inclusions originating from slag lead to the decrease of SiO2 in the inclusions. Due to the low interfacial energy between liquid CAMS inclusions and steel, a few large-size inclusions may be inherited to hot-rolled bars. In light of this, several optimization steps were conducted during BOF tapping and argon-blowing station. After the optimization, large-size CAMS originated form BOF tapping were effectively removed.



中文翻译:

高碳铬轴承钢中大尺寸CaO-Al2O3-MgO-SiO2夹杂物的形成机制

工业实验和热力学分析进行了研究大尺寸(> 30的形成机理μ M)的CaO-Al系2 ö 3 -MgO-的SiO 2(CAMS)在高碳铬轴承钢的夹杂物。发现在整个精炼过程中存在大尺寸的CAMS夹杂物,其中大部分成分位于液体区域。CAMS夹杂物中SiO 2的平均含量从吹氩站的27.5质量%下降到热轧棒材的3.0质量%。Factsage 7.3 计算的结果表明,CAMS 夹杂物来源于夹渣。转炉出钢时,含 60% SiO 2的低碱度炉渣夹杂在钢中并与脱氧产物Al 2 O 3 结合,形成大量液态CAMS夹杂物。在LF精炼过程中,钢水中的[Al]、[Ca]和[Mg]受相应渣组分的活性影响。这三种元素与源自炉渣的CAMS夹杂物中SiO 2之间的反应导致夹杂物中SiO 2的减少。由于液态CAMS夹杂物与钢之间的界面能较低,少数大尺寸夹杂物可能会遗传给热轧棒材。有鉴于此,在转炉出钢和吹氩站期间进行了几个优化步骤。优化后,大尺寸CAMS起源于转炉出钢有效去除。

更新日期:2021-07-14
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