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Discrete geochemical behavior of Sr and Ba in the groundwater of Southern Mor Range, Balochistan, a tracer for igneous and sedimentary rocks weathering and related environmental issues
Applied Geochemistry ( IF 3.1 ) Pub Date : 2021-05-24 , DOI: 10.1016/j.apgeochem.2021.104996
Maria Kaleem , Shahid Naseem , Erum Bashir , Bushra Shahab , Tahir Rafique

A comparative study of Strontium (Sr) and Barium (Ba) along with associated major ions of groundwater was made from the Southern Mor Range, Balochistan, where both igneous and sedimentary rocks are exposed. In the studied samples, Sr2+ varies from 237 to 6,723 with a mean of 1,688 μg/l, while Ba2+ ranged from 40 to 1,332 μg/l with a mean of 207 μg/l. TDS and Sr2+ displayed moderate positive, while Ba2+ showed a slight negative relation. Majority (80.85%) of the samples have existed in the narrow pH range (7.5–8.5). The impact of water-rock interaction is evidenced from the Gibbs diagram; showed influence of igneous and sedimentary rocks on the release of Sr2+ and Ba2+. It is also evidenced from molar ratio of Sr2+/Ca2+, Mg2+/Ca2+, Na+/Cl, Mg2+/Cl of the groundwater. Strontium possessed fairly high relative mobility (RM, av. 0.349) and mobility index (MI, av. 4.38), while RM (av. 0.003) and MI (av. 0.04) of Ba2+ was very low. The saturation indices (SI) plots barite vs. celestite, showed saturation of Ba, while Sr2+ ions are unsaturated. The low Ba2+/Sr2+ (av. 0.208) indicated the existence of aquifer in low elevation areas and the HCO3/Cl ratio (>1) demonstrated a short flow path and speedy flow. The suitability of groundwater was assessed for drinking purpose as per World Health Organization (WHO) and Expanded Programme on Immunization (EPI) guidelines and possible environmental issues were discussed.



中文翻译:

Sr和Ba在Bal路支斯坦南部莫尔山脉的地下水中的离散地球化学行为,火成岩和沉积岩风化和相关环境问题的示踪剂

对Bal(Sr)和钡(Ba)以及相关的地下水主要离子的比较研究是在Bal路支省的南部莫尔山脉进行的,火成岩和沉积岩都暴露在其中。在所研究的样品中,Sr 2+从237到6,723不等,平均值为1,688μg/ l,而Ba 2+在40到1,332μg/ l范围内,平均值为207μg / l。TDS和Sr 2+表现出中等程度的阳性,而Ba 2+表现出轻微的负相关。大部分(80.85%)样品存在于狭窄的pH范围(7.5–8.5)中。吉布斯图证明了水-岩相互作用的影响。表现出火成岩和沉积岩对Sr 2+和Ba 2+释放的影响。它也被选自Sr的摩尔比证明2+ /钙2+,2+ /钙2+,钠+ /氯- ,镁2+ /氯-地下水。锶具有相当高的相对迁移率(RM,平均0.349)和迁移率指数(MI,平均4.38),而Ba 2+的RM(平均0.003)和MI(平均0.04)非常低。饱和指数(SI)绘制重晶石与天青石的关系曲线,表明Ba处于饱和状态,而Sr 2+离子是不饱和的。低的Ba 2+ / SR 2+(AV 0.208)表明含水层在低海拔地区的存在和HCO 3 - /氯比率(> 1)显示出较短的流动路径和快速的流动。根据世界卫生组织(WHO)评估了地下水是否适合饮用,并讨论了扩大免疫规划(EPI)指南,并讨论了可能的环境问题。

更新日期:2021-05-27
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