当前位置: X-MOL 学术J. Inorg. Organomet. Polym. Mater. › 论文详情
Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)
Ternay Au@TiO 2 /α-Fe 2 O 3 Nanocomposite with Nanoring Structure: Synthesis, Characterization and Photocatalytic Activity
Journal of Inorganic and Organometallic Polymers and Materials ( IF 3.9 ) Pub Date : 2021-05-22 , DOI: 10.1007/s10904-021-02033-x
Amine Mezni , Mohamed M. Ibrahim , Nesrine Ben Saber , Mohammed Alsawat , Tushar Kumeria , Tariq Altalhi

In the present study, a modified solvothermal reaction of (hematite) with titanium(IV) butoxide and gold(III) chloride produced ternary Au@TiO2/α-Fe2O3 nanocomposite. The designed Au@TiO2/α-Fe2O3 photocatalyst exhibits nanoring-like structure with high crystallinity indicating the possibility of manufacturing extreme structures and offering a new nanostructure that was not previously studied. Both TiO2 and Au nanoparticles (NPs) were found to be dispersed uniformly on the α-Fe2O3 surface. X-ray diffraction powder technique combined with X-ray photoelectron (XPS) and Raman spectroscopy confirm the formation of the three materials with cubic Au, anatase TiO2 and hematite α-Fe2O3 structures, respectively. The photocatalytic activity proves the performance of this ternary heterojunction to decomposes different pollutants. It was found that, TiO2 absorbs UV-light, α-Fe2O3 absorbs both UV and Visible light and plasmonic gold NPs work as an electron mediator and therefore exhalt the photocatalytic efficiency of the ternary Au@TiO2/α-Fe2O3 photocatalyst. The present work delivers a novel perception to develop a stable photocatalyst based metal oxide/noble-metal hetero-nanostructure for the degradation of different types of pollutants in the industrial zones.



中文翻译:

具有纳米环结构的Ternay Au @ TiO 2 /α-Fe2 O 3纳米复合材料:合成,表征和光催化活性

在本研究中,(赤铁矿)的钛(IV)和叔丁醇钾金(III),氯化改性溶剂热反应产生的三元金@的TiO 2 /的α-Fe 2 ö 3纳米复合物。所设计的Au @的TiO 2 /的α-Fe 2 ö 3光催化剂表现出纳米环状结晶性高,指示制造极端结构,并提供了以前未研究一个新的纳米结构的可能性的结构。两者的TiO 2被发现和Au纳米颗粒(NP)要在上均匀地分散的α-Fe 2 ö 3表面。X-射线衍射粉末技术用X射线光电子(XPS)和拉曼光谱确认形成三种材料的立方的Au组合,锐钛矿二氧化钛2和赤铁矿的α-Fe 2层ö 3的结构,分别。光催化活性证明了该三元异质结具有分解不同污染物的性能。据发现,二氧化钛2吸收UV光,的α-Fe 2 ö 3吸收UV和可见光和等离子体激元金NP工作作为电子介体,并因此exhalt三元金@ TiO 2的光催化效率2 /的α-Fe 2 ö 3光催化剂。本工作提供了一种新颖的见解,以开发一种稳定的基于光催化剂的金属氧化物/贵金属异质纳米结构,以降解工业区中不同类型的污染物。

更新日期:2021-05-22
down
wechat
bug