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Strengthening mechanism of CoCrNiMox high entropy alloys by high-throughput nanoindentation mapping technique
Intermetallics ( IF 4.3 ) Pub Date : 2021-05-21 , DOI: 10.1016/j.intermet.2021.107209
Yonggang Tong , Hao Zhang , Hongfeng Huang , Lingwei Yang , Yongle Hu , Xiubing Liang , Manyu Hua , Jian Zhang

A novel nanoindentation mapping technique was employed to correlate the microstructure, composition and mechanical properties of the fcc, laves and lamellae in CoCrNiMox high-entropy alloys with varying Mo content. The results suggest that the Young's modulus of the 3 constituents were comparable, averaging ≈230 GPa. Despite this, the hardness was quite different. The fcc phase in CoCrNiMox was mainly strengthened by a solute strengthening mechanism, and the hardness was increased from ≈3.98 GPa to ≈4.45 GPa, as the atomic percentage of Mo in fcc increased from ≈7.4% to 15.4%. A solute strengthening model a accounting lattice distortion was employed to correlate the strengthening effect in fcc with Mo content. The laves phase was rich in Mo composition (≈28.6%) and exhibited an ultrahigh hardness, ≈9.13 GPa, which was ≈2 times higher than that of fcc phase. Finally, the lamellae colonies, made up by alternative fcc and laves phases, had an intermediate hardness, ≈6.36 GPa. This was well explained by a rule-of-mixture model.



中文翻译:

高通量纳米压痕测绘技术强化CoCrNiMo x高熵合金的机理

一种新颖的纳米压痕测绘技术被用来关联Mo含量不同的CoCrNiMo x高熵合金中fcc,熔渣和片晶的微观结构,组成和力学性能。结果表明,这三种成分的杨氏模量相当,平均≈230GPa。尽管如此,硬度还是有很大不同。CoCrNiMo x中的fcc相钼主要通过溶质强化机制得到强化,并且随着fcc中Mo的原子百分比从≈7.4%增加到15.4%,硬度从≈3.98GPa增加到≈4.45GPa。采用考虑晶格畸变的溶质强化模型,将fcc的强化效果与Mo含量相关联。Laves相含有丰富的Mo成分(约28.6%),并且具有超高硬度,约9.13 GPa,是fcc相的约2倍。最后,由交替的fcc和laves相组成的片状菌落具有中等硬度,≈6.36GPa。混合规则模型很好地解释了这一点。

更新日期:2021-05-22
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