Ru-TsDPEN catalysts and derivatives in asymmetric transfer hydrogenation reactions,Chirality

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Ru-TsDPEN catalysts and derivatives in asymmetric transfer hydrogenation reactions
Chirality ( IF 2.8 ) Pub Date : 2021-05-19 , DOI: 10.1002/chir.23317
Ashish A. Mishra ₁ , Bhalchandra M. Bhanage ₁

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This review summarizes current developments, novel synthetic routes for Ruthenium tethered chiral catalyst, and its derivatives along with its application in asymmetric synthesis. The review also covers derivatization in tethering unit, modification in N-monofunctionalized ligand as well as ligation of other ligand with Ru metal in chiral catalyst. Apparently, the effect of a modified tethered catalyst in the enantioselective synthesis of chiral products as well as in synthetic chemistry is also discussed in detail.

中文翻译：

Ru-TsDPEN催化剂及其衍生物在不对称转移加氢反应中的应用

本综述总结了钌系手性催化剂及其衍生物的当前发展、新合成路线及其在不对称合成中的应用。该评论还涵盖了系链单元中的衍生化、N-单功能化配体的修饰以及其他配体与手性催化剂中的 Ru 金属的连接。显然，还详细讨论了改性系留催化剂在手性产物的对映选择性合成以及合成化学中的作用。

更新日期：2021-06-08

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