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Melting and Crystallization of High- and Low-Density Polyethylenes in Mixtures with Some Oxides and Ionic Crystals after Intensive Plastic Deformation
Protection of Metals and Physical Chemistry of Surfaces ( IF 1.1 ) Pub Date : 2021-05-15 , DOI: 10.1134/s2070205121020118
V. A. Zhorin , M. R. Kiselev , V. A. Kotenev

Abstract

Mixtures of high-density polyethylene and low-density polyethylene with 90 wt % adamantane, cyanuric acid, BeO, SiO2, KF, AgI, and AgNO3 were subjected to plastic deformation under a pressure of 1 GPa on an anvil-type high-pressure apparatus and studied by DSC. The endothermic processes were associated with the destruction of intermolecular bonds at the filler–polymer interfaces caused by the formation of double electric layers and the occurrence of interphase electrostatic interaction.



中文翻译:

强塑性变形后高密度聚乙烯和低密度聚乙烯与某些氧化物和离子晶体的混合物的熔融和结晶

摘要

将高密度聚乙烯和低密度聚乙烯与90%的金刚烷,氰尿酸,BeO,SiO 2,KF,AgI和AgNO 3的混合物在1 GPa的压力下在砧型高密度聚乙烯上进行塑性变形。压力仪并由DSC研究。吸热过程与由于双电层的形成和相间静电相互作用的发生而导致的填料-聚合物界面分子间键的破坏有关。

更新日期:2021-05-17
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