Two novel complexes, namely [Cu₂(L)₂] (1) and [Ni₄(L)₄] (2, H₂L = 1-{3-[(5-bromo-2-hydroxy-benzylidene)-amino]-2-hydroxyphenyl}-ethanone) were synthesized through solvothermal methods at the same condition. The complexes 1 and 2 were characterized by IR spectroscopy, elemental analysis and single-crystal X-ray diffraction. 1 is dinuclear copper complex while 2 is a cubane nickel cluster. The L ligand displays two different coordination modes. One is the μ₁-L-κ³N¹:O¹:N² coordination mode and the other is μ₃-L-κ⁶O¹:O²:O²:O²:N¹:O³ coordination mode. Magnetic studies reveal that the complex 2 displays dominant antiferromagnetic intracluster interactions between the Ni^II ions through the μ₃ oxide bridges with g = 2.29, J = − 0.939 cm⁻¹, and zJ′ = − 0.333 cm⁻¹. Hirshfeld surface analysis revealed that H···H interaction was the dominant intermolecular interaction.

两种新颖的络合物，即[Cu ₂（L）₂ ]（1）和[Ni ₄（L）₄ ]（2，H ₂ L  = 1- {3-[（5-溴-2-羟基-亚苄基）-在相同条件下通过溶剂热法合成了氨基] -2-羟苯基}-乙酮。配合物1和2通过红外光谱，元素分析和单晶X射线衍射表征。1是双核铜络合物，而2是古巴镍簇。的大号配体显示两个不同的配位模式。一个是μ ₁ -大号- κ ³ Ñ ¹：o ¹：N ²配位模式，另一种是μ ₃ -大号- κ ⁶ ø ¹：o ²：o ²：o ²：N ¹：o ³配位模式。磁性的研究表明，该配合物2个在Ni之间显示显性反铁磁相互作用群集内^II通过离子μ ₃氧化物桥与克 = 2.29，Ĵ ＝-0.939cm ^-1，并且zJ′  ＝- 0.333cm ^-1。Hirshfeld表面分析表明，H···H相互作用是主要的分子间相互作用。