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Spectral line-shape analysis of CO2 transition using Hartmann-Tran profile and its asymptotic limits
Journal of Molecular Spectroscopy ( IF 1.4 ) Pub Date : 2021-05-11 , DOI: 10.1016/j.jms.2021.111480
Dong Li , Ruimin Guo , Hewei Dong

In this paper, the Hartmann-Tran profile (HTP) and its asymptotic limits are employed to analyze the experimentally-measured absorption spectra of CO2 gas. The fitted results by multi-spectrum fitting are compared to those from the ordinary line-shape models. The equivalence and computational efficiency of the asymptotic limits of HTP to their ordinary counterparts are studied. The research shows that the parameters of line position ω0, intensity S, pressure broadening coefficient Γ0/p and shifting coefficient Δ0/p by HTP agree well with those from the speed-dependent hard-collision line-shapes. In comparison, the poorly-determined partial-correlation parameter η makes the fitted line-narrowing parameters less reliable.



中文翻译:

利用Hartmann-Tran谱及其渐近极限分析CO 2跃迁的谱线形

本文采用Hartmann-Tran谱(HTP)及其渐近极限来分析实验测量的CO 2气体吸收光谱。将多光谱拟合的拟合结果与普通线形模型的拟合结果进行比较。研究了HTP渐近极限与其普通对应极限的等价性和计算效率。研究表明线位置参数ω0, 强度 小号,压力展宽系数 Γ0/p 和移动系数 Δ0/pHTP的“线性”与速度依赖的硬碰撞线形的速度非常吻合。相比之下,偏相关参数不确定η 使得拟合的线变窄参数不太可靠。

更新日期:2021-05-20
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