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Investigation of the Process of Synthesizing Nanosized Nickel Powders by Hydrogen Reduction Under Nonisothermal Conditions
Metallurgist ( IF 0.8 ) Pub Date : 2021-05-10 , DOI: 10.1007/s11015-021-01149-2
V. M. Nguyen , T. H. Nguyen

We study the kinetic characteristics and properties of the product of the process of synthesizing nickel nanopowders by the hydrogen reduction of Ni(OH)2 hydroxide compound under nonisothermal conditions. It is shown that the process of hydrogen reduction of the nanopowder of Ni(OH)2 hydroxide takes place within the temperature range 210–300°C with the maximal specific rate equal to 9.44·10−8 kg/sec recorded at a temperature of 285°C. The activation energy of the process of reduction of Ni(OH)2 nanopowder under nonisothermal conditions was estimated as ≈ 54 kJ/mole, which confirms the kinetic conditions of limiting of the process. It is shown that the elevation of temperature up to 285°C enables us to efficiently increase the rate of the total process of hydrogen reduction of Ni(OH)2 nanopowder (with guaranteeing high quality of the products of reduction). The obtained Ni nanoparticles mainly have round shapes and the sizes from ten to several tens of nanometers with a mean value of 50 nm.



中文翻译:

非等温条件下氢还原合成纳米镍粉的工艺研究

我们研究了在非等温条件下通过氢还原Ni(OH)2氢氧化物化合物合成镍纳米粉体过程的产物的动力学特性和性能。结果表明,Ni(OH)2氢氧化物纳米粉体的氢还原过程是在210–300°C的温度范围内发生的,最大比重等于9.44·10 -8 kg / sec。 285℃。Ni(OH)2还原过程的活化能非等温条件下的纳米粉估计为≈54 kJ / mol,这证​​实了限制该过程的动力学条件。结果表明,温度升高到285°C使我们能够有效提高Ni(OH)2纳米粉氢还原全过程的速率(同时保证还原产物的高质量)。所获得的Ni纳米颗粒主要为圆形,尺寸为十至几十纳米,平均值为50nm。

更新日期:2021-05-10
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