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Large electromechanical strain response in BiFeO3–BaTiO3-based ceramics at elevated temperature
Journal of Physics and Chemistry of Solids ( IF 4.3 ) Pub Date : 2021-05-09 , DOI: 10.1016/j.jpcs.2021.110133
Salman Ali Khan , Tauseef Ahmed , Muhammad Habib , Fazli Akram , Jihee Bae , Tae Kwon Song , Dong Hwan Lim , Soon-Jong Jeong , Myong-Ho Kim , Soonil Lee

An approach of composition modification in (Bi,Na,Ba,Sr)(Ti,Nb,Zr)O3 (BNSTNZ)–modified 0.65Bi1.05FeO3–0.35BaTiO3 (BF35BT) piezoelectric materials was investigated. Introducing BNSTNZ into BF35BT ceramics led from the normal-ferroelectric to relaxor-ferroelectric- phase. At the optimum composition, large dynamic piezoelectric coefficient (d33*) of 583 pm/V under the applied field of 5 kV/mm and relatively high static piezoelectric coefficient (d33) of 135 pC/N with high maximum temperature (Tm ≤ 400 °C) were obtained. The unipolar strain and d33* of BNSTNZ into BF35BT ceramics with x = 0.005 increased up to 0.251% and 718 pm/V at 90 °C. The remarkably enhanced field-induced strain response of BF35BT-based compositions is believed to be attributed to the optimum grain size, high tetragonality and the ferroelectric-relaxor phase coexistence. It is noted that this composition can be a favorable lead-free candidate for high-temperature piezoelectric applications.



中文翻译:

在大的BiFeO机电应变响应3 -BaTiO 3个在升高的温度为基础的陶瓷

研究了在(Bi,Na,Ba,Sr)(Ti,Nb,Zr)O 3(BNSTNZ)改性的0.65Bi 1.05 FeO 3 –0.35BaTiO 3(BF35BT)压电材料中进行成分改性的方法。将BNSTNZ引入到BF35BT陶瓷中,从普通铁电到松弛铁电。在最佳组成下,在5 kV / mm的施加电场下,动态压电系数(d 33 *)为583 pm / V,在最高温度(T m)为较高时,静态压电系数(d 33)为135 pC / N。 ≤400°C)。单极应变和d 33* 在90°C下,将x = 0.005的BNSTNZ添加到BF35BT陶瓷中,可提高至0.251%和718 pm / V。据认为,基于BF35BT的组合物的场致应变响应显着增强,这归因于最佳晶粒尺寸,高四方性和铁电松弛相共存。注意,该组合物可以是用于高温压电应用的有利的无铅候选物。

更新日期:2021-05-14
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