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Achieving ultra-high ductility and fracture toughness in molybdenum via Mo2TiC2 MXene addition
Materials Science and Engineering: A ( IF 6.1 ) Pub Date : 2021-05-08 , DOI: 10.1016/j.msea.2021.141422
Xuan Chen , Rui Li , Bin Li , Juan Wang , Tao Wang , Fuxue Yan , Guojun Zhang

Low ductility and toughness of molybdenum (Mo) alloys have usually been the bottleneck for their further application. Here, the improved strength together with ultra-high ductility and fracture toughness of Mo alloys were achieved by the incorporation of Mo2TiC2 (a typical MXene). Elongation of Mo–Mo2TiC2 alloys increased to 2.3–2.7 folds of pure Mo and the fracture toughness increased to 2.4 folds when Mo2TiC2 content rose to 2 wt%. Also, yield strength and tensile strength of Mo–Mo2TiC2 alloys increased slightly compared with pure Mo. The relationship between microstructural features and deformation behavior in Mo–Mo2TiC2 alloys was discussed to account for the toughening mechanisms, among which the high relative density, grain refinement, high low-angle grain boundaries (LGBs) proportion and strain hardening rate were the main reasons for the superior ductility (elongation, 39.4%–46.5%) in Mo–Mo2TiC2 alloys. Besides, the ultra-high toughness of Mo–Mo2TiC2 alloys was originated from not only the plastic deformation capacity, but also the crack deflection, particles pull-out and secondary cracking.



中文翻译:

通过添加Mo 2 TiC 2 MXene实现钼的超高延展性和断裂韧性

钼(Mo)合金的低延展性和韧性通常是其进一步应用的瓶颈。在此,通过引入Mo 2 TiC 2(典型的MXene),实现了Mo合金的提高的强度以及超高的延展性和断裂韧性。当Mo 2 TiC 2含量增加到2 wt%时,Mo–Mo 2 TiC 2合金的伸长率增加到纯Mo的2.3–2.7倍,断裂韧性增加到2.4倍。此外,Mo-Mo 2 TiC 2合金的屈服强度和拉伸强度比纯Mo略有增加。Mo-Mo的微观结构特征与变形行为之间的关系讨论了2 TiC 2合金的增韧机理,其中高相对密度,晶粒细化,高低角晶界(LGBs)比例和应变硬化率是产生优异延展性的主要原因(伸长率为39.4% ––46.5%)在Mo–Mo 2 TiC 2合金中。此外,Mo-Mo 2 TiC 2合金的超高韧性不仅来自塑性变形能力,还归因于裂纹变形,颗粒脱落和二次裂纹。

更新日期:2021-05-18
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