Journal of Applied Spectroscopy ( IF 0.8 ) Pub Date : 2021-05-08 , DOI: 10.1007/s10812-021-01179-3 S. S. Golik , A. Yu. Mayor , V. V. Lisitsa , Yu. S. Tolstonogova , A. A. Ilyin , A. V. Borovskiy , O. A. Bukin
The capabilities of filament-induced breakdown spectroscopy for the analysis of the elemental composition of aqueous aerosols were estimated. The diameter of aqueous aerosol droplets in the atmosphere was 0.8–2.0 μm. The emission lines of the chemical elements were excited by fi lamentation of femtosecond laser pulses (60 fs, 800 nm, 4.4 mJ) in weak focusing mode by a lens with a focal length of 500 mm. The obtained limits of detection for Al (396.15 nm), Ba (553.35 nm), Ca (422.67 nm), Mg (285.21 nm), Na (588.99 nm), and Mn (403.08 nm) in an aqueous aerosol were 12.1, 41.7, 10.0, 7.3, 0.7, and 32.3 mg/L, respectively.
中文翻译:
细丝诱导的击穿光谱中水气溶胶中化学元素的检测极限
估计了灯丝诱导的击穿光谱法分析水性气溶胶元素组成的能力。大气中的水雾滴直径为0.8–2.0μm。通过使用焦距为500 mm的透镜以弱聚焦模式对飞秒激光脉冲(60 fs,800 nm,4.4 mJ)进行纤丝激发,激发化学元素的发射线。水性气溶胶中的Al(396.15 nm),Ba(553.35 nm),Ca(422.67 nm),Mg(285.21 nm),Na(588.99 nm)和Mn(403.08 nm)的检测限分别为12.1、41.7和41.7。 ,10.0、7.3、0.7和32.3 mg / L。