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Effects of accelerators, and metal salts on the hydrolysis of sodium tetrahydroborate: A kinetic and mechanistic study for hydrogen generation
Journal of Saudi Chemical Society ( IF 5.8 ) Pub Date : 2021-05-07 , DOI: 10.1016/j.jscs.2021.101258
Zaheer Khan , Shaeel Ahmad AL-Thabaiti

Sodium tetrahydroborate (NaBH4) was used as a fuel source for hydrogen-oxygen fuel cell. The oxalic acid, Ag+, Cu2+ and Ni2+ accelerates the hydrogen (H2 gas) evolution from the self-hydrolysis of NaBH4 at 30 °C. Kinetics of H2 gas generation was evaluated as a function of catalyst, NaBH4, sodium hydroxide concentrations at different temperatures. Hydrolysis NaBH4 follows first-, and fractional-order kinetics with [BH4-], and [H+] respectively. The hydrolysis of NaBH4 decreases with increasing [NaOH] at 30 °C. The metal ions (Ag+, Cu2+, and Ni2+) catalyzed the evolution of H2 gas and hydrolysis followed zero-order kinetics with respect to the metal ions. Hydrolysis of NaBH4 was catalyzed by metal ions and hydrogen ions simultaneously. The activation parameters were calculated and found to be activation energy = 54.9, 59.7, 62.7 kJ/mol, enthalpy of activation = 52.4, 57.5, 60.2 kJ/mol and entropy of activation = −62.2, −48.2, −49.6 J/K/mol for Ag+, Cu2+ and Ni2+, respectively. The catalytic activity of depends on the reduction potential of metal ions; Ag+ (0.799 V) ˃ Cu2+ (0.341 V) ˃ Ni2+ (−0.257).



中文翻译:

促进剂和金属盐对四氢硼酸钠水解的影响:制氢的动力学和机理研究

四氢硼酸钠(NaBH 4)被用作氢氧燃料电池的燃料源。草酸,Ag +,Cu 2+和Ni 2+会加速NaBH 4在30°C时的自水解作用而释放出氢气(H 2气体)。根据催化剂,NaBH 4,不同温度下的氢氧化钠浓度评估了H 2气体生成的动力学。水解的NaBH 4如下一阶,以及与[BH分数阶动力学4 - ],和[H + ]分别。NaBH 4的水解在30°C时,随着[NaOH]的增加而降低。金属离子(Ag +,Cu 2+和Ni 2+)催化H 2气体的释放,并且水解遵循相对于金属离子的零级动力学。金属离子和氢离子同时催化NaBH 4的水解。计算出活化参数,发现活化能= 54.9、59.7、62.7kJ / mol,活化焓= 52.4、57.5、60.2kJ / mol,活化熵= -62.2,-48.2,-49.6J / K /对于Ag +,Cu 2+和Ni 2+分别为mol 。的催化活性取决于金属离子的还原电势。Ag +(0.799 V)˃铜2+(0.341 V)˃Ni 2 +(-0.257)。

更新日期:2021-05-22
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