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Enhancing the separation and antifouling properties of PES nanofiltration membrane by use of chitosan functionalized magnetic nanoparticles
Korean Journal of Chemical Engineering ( IF 2.9 ) Pub Date : 2021-05-06 , DOI: 10.1007/s11814-021-0765-9
Farhad Zareei , Samaneh Bandehali , Sayed Mohsen Hosseini

Chitosan functionalized (CoFe2O4−CuO) composite nanoparticles were synthesized and then used in fabrication of PES-based nanofiltration membranes. X-ray diffraction, Fourier transform infrared spectroscopy and scanning electron microscopy were used for the characterization of synthesized nanoparticles. The fabricated membranes were also characterized by scanning electron microscopy, 3D surface images, water contact angle, membrane porosity, pure water flux, salt rejection and fouling resistance consideration. Obtained results revealed that water contact angle was reduced significantly from 65° for the neat membrane to 36° for M5 with 1.0 wt% composite nanoparticles. All modified membranes also showed higher water flux and salt rejection than virgin PES membrane. The highest pure water flux measured 45.2 L/m2h and the highest salt rejection measured 88% for the modified membranes containing of composite nanoparticles. The modified membranes showed outstanding antifouling ability. The flux recovery ratio enhanced from 40% for pristine membrane to 93% for the modified ones with 0.5 wt% of Cs-functionalized (CoFe2O4/CuO) composite nanoparticles.



中文翻译:

利用壳聚糖功能化的磁性纳米粒子增强PES纳滤膜的分离和防污性能

壳聚糖功能化(CoFe 2 O 4合成了-CuO)复合纳米粒子,然后将其用于基于PES的纳滤膜的制造。X射线衍射,傅立叶变换红外光谱和扫描电子显微镜用于表征合成的纳米颗粒。所制造的膜还通过扫描电子显微镜,3D表面图像,水接触角,膜孔隙率,纯净水通量,脱盐率和耐污染性来表征。获得的结果表明,水接触角从纯膜的65°显着降低到含1.0 wt%复合纳米粒子的M5的36°。与原始的PES膜相比,所有改性膜还显示出更高的水通量和脱盐率。测得的最高纯水通量为45.2 L / m 2含复合纳米颗粒的改性膜的h和最高的脱盐率测量为88%。改性膜表现出优异的防污能力。具有0.5 wt%的Cs官能化(CoFe 2 O 4 / CuO)复合纳米粒子的通量回收率从原始膜的40%提高到改性膜的93%。

更新日期:2021-05-07
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