Journal of Electroceramics ( IF 1.7 ) Pub Date : 2021-05-06 , DOI: 10.1007/s10832-021-00236-9 Trang An Duong , Farruhk Erkinov , Hoang Thien Khoi Nguyen , Chang Won Ahn , Byeong Woo Kim , Hyoung-Su Han , Jae-Shin Lee
The formation of a morphotropic phase boundary (MPB) in piezoelectric ceramics is one of the most important techniques to enhance their dielectric and piezoelectric properties. In this work, a rhombohedral (R) and tetragonal (T) phase boundary has been designed and clarified using the lead‒free 0.92(Na0.5K0.5)NbO3–(0.08–x)(Bi0.5Li0.5)TiO3–xBaZrO3 ternary system. The R-T phase coexistence region is identified in the ceramics with 0.06 ≤ x ≤ 0.07. We successfully demonstrated that the crystal’s relatively enhanced d33 and its excellent temperature stability are originated from phase transition behaviors that were confirmed by the temperature‒dependent dielectric properties and X−ray diffraction (XRD) patterns.
中文翻译:
BaZrO 3改性无铅KNN-BLT陶瓷的变质相界上的温度不敏感压电特性
压电陶瓷中形变相界(MPB)的形成是提高其介电和压电性能的最重要技术之一。在这项工作中,使用无铅0.92(Na 0.5 K 0.5)NbO 3 –(0.08– x)(Bi 0.5 Li 0.5)TiO 3 – x BaZrO 3三元系。所述RT相共存区域在陶瓷识别与0.06≤ X ≤0.07。我们成功地证明了晶体的相对增强d 33 其出色的温度稳定性源于相变行为,该相变行为由与温度相关的介电特性和X射线衍射(XRD)图案证实。