The phosphorus-containing heterocycles are an important class of compounds in organic chemistry. Because of their potential application in many fields, especially, the synthetic pesticides, medicine and catalyst, the phosphorus-containing heterocycles have attracted continuous attention from organic synthesis scientists. The development of efficient and low-cost catalytic systems is of great interest for the construction of heterocycles C-P bond. Usually, the phosphorus-containing heterocycles is prepared via direct carbon–hydrogen (C-H) bond activation or pre-functionalized of heterocycles with phosphorus-hydrogen (P-H) bond of phosphorus compounds reaction by metal-catalyzed. This review summarizes recent progress in the heterocycles C-P bond formation reactions by metal-catalyzed, which mainly focus on the discussion of the reaction mechanism. It aims to provide efficient methods for the future synthesis and application in this field.

含磷杂环是有机化学中一类重要的化合物。由于其在许多领域的潜在应用，特别是合成农药、医药和催化剂，含磷杂环化合物一直受到有机合成科学家的关注。开发高效且低成本的催化体系对于构建杂环CP键具有重要意义。通常，含磷杂环是通过直接碳氢 (CH) 键活化或通过金属催化的磷化合物反应的磷氢 (PH) 键对杂环进行预官能化制备的。本文综述了金属催化杂环CP键形成反应的最新进展，主要集中讨论了反应机理。