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Carboxylate-Functionalized P, N-Ligated Cobalt Catalysts for Alkene Hydrosilylation
Current Organic Synthesis ( IF 1.7 ) Pub Date : 2021-07-31 , DOI: 10.2174/1570179417666201214112514 Yangyang Ma 1 , Jiayun Li 1 , Ying Bai 1 , Jiajian Peng 1
中文翻译：
用于烯烃氢化硅烷化的羧酸盐官能化 P、N-配位钴催化剂
更新日期：2021-08-30
Current Organic Synthesis ( IF 1.7 ) Pub Date : 2021-07-31 , DOI: 10.2174/1570179417666201214112514 Yangyang Ma 1 , Jiayun Li 1 , Ying Bai 1 , Jiajian Peng 1
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A series of N, P-ligands bearing carboxyl groups have been synthesized. These have been applied in conjunction with cobalt naphthenate in a facile, economic, and efficient method for the catalytic hydrosilylation of alkenes. In the presence of KOtBu as an additive, the reaction time and activation energy are greatly reduced.
中文翻译：
用于烯烃氢化硅烷化的羧酸盐官能化 P、N-配位钴催化剂
已经合成了一系列带有羧基的 N、P-配体。这些已与环烷酸钴一起应用于烯烃催化氢化硅烷化的简便、经济和有效的方法中。在 KO t Bu 作为添加剂存在的情况下，反应时间和活化能大大降低。
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