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Lithium and sodium ion-exchange behavior of (H3O)Zr2(PO4)3 with three-dimensional network structure
Solid State Communications ( IF 2.1 ) Pub Date : 2021-05-06 , DOI: 10.1016/j.ssc.2021.114356
Chihiro Minamoto , Susumu Nakayama

The ion-exchange behavior of H3O+ in (H3O)Zr2(PO4)3 and alkali metal ions, MI+, was examined in an aqueous solution. The pH titration was performed using a 0.1 mol·L−1-MIOH solution (MI = Li, Na, K, Rb, and Cs), while stirring and distributing (H3O)Zr2(PO4)3 in deionized water. In K, Rb, and Cs, the pH value increased to ten or more after adding the MIOH solution. Therefore, it was believed that ionic exchange with H3O+ in (H3O)Zr2(PO4)3 did not advance. Conversely, ionic exchange with H3O+ was observed at Li and Na. In Li only or Na only, Li was easily immobilized and leached, and Na was inferior to Li. In Li + Na, the immobilized amount of Li decreased, Li leaching was difficult, and the immobilized amount of Na increased.



中文翻译:

具有三维网络结构的(H 3 O)Zr 2(PO 43的锂和钠离子交换行为

在水溶液中检查了(H 3 O)Zr 2(PO 43中的H 3 O +和碱金属离子M I +的离子交换行为。使用0.1mol·L -1 -M I OH溶液(M I  = Li,Na,K,Rb和Cs)进行pH滴定,同时搅拌并分配(H 3 O)Zr 2(PO 43在去离子水中。在K,Rb和Cs,pH值增加至十个或更多个添加所述M后OH溶液。因此,据信与H 3 O的离子交换+中(H 3 O)的Zr 2(PO 43没有推进。相反,在Li和Na处观察到与H 3 O +的离子交换。在仅Li或仅Na中,Li容易被固定和浸出,并且Na劣于Li。在Li + Na中,Li的固定化量减少,Li的浸出困难,并且Na的固定化量增加。

更新日期:2021-05-10
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