Catalysis Communications ( IF 3.4 ) Pub Date : 2021-04-29 , DOI: 10.1016/j.catcom.2021.106320 Xiaofeng Zhu , Bingyang Bai , Bin Zhou , Shengfu Ji
Nanosized Co3O4 with different morphologies (rods-like (NR-), flowers-like (NF-), cages-like (NC-) and single crystal (NP-)) were synthesized by using hydrothermal and co-precipitation methods and applied in catalytic removal of ethyl acetate (EA). Complete EA conversion under a space velocity of 30,000 mL/ (g h) are shown at 210 °C for NP-Co3O4. The results of physicochemical properties reveals that NP-Co3O4 catalyst performs the best catalytic activity for EA oxidation attributed to larger specific surface area, better low-temperature reducibility, abundant Co3+ cationic species exposed on the (220) plane and sufficiently active surface oxygen species.
中文翻译:
具有不同形态的Co 3 O 4纳米颗粒用于乙酸乙酯的催化去除
利用水热共沉淀法合成了不同形态的纳米Co 3 O 4(棒状(NR-),花状(NF-),笼状(NC-)和单晶(NP-))。并用于催化去除乙酸乙酯(EA)。对于NP-Co 3 O 4,在210°C下,空速为30,000 mL /(g h)时,EA完全转化。物化性质的结果表明,NP-Co 3 O 4催化剂对EA氧化表现出最佳的催化活性,这归因于较大的比表面积,更好的低温还原性,在(220)平面上暴露的丰富的Co 3+阳离子种类以及足够的活性表面氧种类。