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Natural clay loaded Sm2MoO6 nanocomposite, a green catalyst, for multiple applications
Nano-Structures & Nano-Objects Pub Date : 2021-04-29 , DOI: 10.1016/j.nanoso.2021.100744
Murugan Kumaresan , Tata Sanjay Kanna Sharma , Kuo Yuan Hwa , Vadivel Saravanan , Ponnusamy Sami , Meenakshisundaram Swaminathan

In the present work, multiple applications of natural clay loaded Samarium molybdate for photodegradation, sensing and antibacterial activity were analyzed. The clay-based materials have attracted great attention as they show good application prospects for environmental remediation. We developed natural clay loaded Sm2MoO6 (CSm2MoO6) nanocomposite, hydrothermally and characterized by XRD, SEM, HR-TEM, FT-IR and optical studies. XRD pattern of CSm2MoO6 exhibits peaks at 19.60, 27.80, 35.60 and 62.40 corresponding to clay and Sm2MoO6 peaks clearly indicates the formation of natural clay conjugated with Sm2MoO6. SEM image of the natural clay doped CSm2MoO6 nanoparticle shows a homogeneous distribution of spherical Sm2MoO6on nanoflakes of clay material. HR-TEM images reveal that the average particle size is 50 nm. Loading of natural clay material increased the visible absorption of Sm2MoO6 by reducing the band gap from 3.82 to 2.39 eV. Decomposition of 20 ppm of Metronidazole (MNZ) was 95% with 60 mg of CSm2MoO6 in 100 min of visible light illumination. Hydroxyl radicals played the main role for photodegradation of MNZ. Electrochemical analysis revealed that the oxidation peak current of 4-aminophenol has increased with a high potential at pH 6.0 and CSm2MoO6/SPCE electrode has an advantage of low detection limit of 0.005 μM and a long linear range of 2949.72 μM with a sensitivity of 5.29301 μM. The synthesized nanocomposite has a significant bactericidal activity against Bacillus subtilis, Staphylococcus aureus, Proteus mirabilis, Bacteroides fragilis, E. coli and Candida albicans. These results make this green catalyst potential for multiple applications.



中文翻译:

天然粘土负载的Sm 2 MoO 6纳米复合材料,一种绿色催化剂,可用于多种应用

在目前的工作中,分析了天然粘土负载的钼酸mar在光降解,传感和抗菌活性方面的多种应用。粘土基材料因其在环境修复方面显示出良好的应用前景而备受关注。我们开发了水热天然负载粘土的Sm 2 MoO 6(CSm 2 MoO 6)纳米复合材料,并通过XRD,SEM,HR-TEM,FT-IR和光学研究进行了表征。CSm 2 MoO 6的XRD图谱显示出在19.60、27.80、35.60和62.40处的峰,分别对应于粘土和Sm 2 MoO 6峰,清楚地表明了与Sm 2共轭的天然粘土的形成。MoO 6。天然粘土掺杂的CSm 2 MoO 6纳米颗粒的SEM图像显示球形Sm 2 MoO 6在粘土材料的纳米薄片上的均匀分布。HR-TEM图像显示平均粒径为50 nm。通过将带隙从3.82 eV减小到2.39 eV ,天然粘土材料的负载增加了Sm 2 MoO 6的可见吸收。用60 mg CSm 2 MoO 6分解20 ppm甲硝唑(MNZ)的95%在100分钟的可见光照射下。羟基自由基在MNZ的光降解中起主要作用。电化学分析表明4-氨基苯酚的氧化峰电流在pH 6.0时以高电势增加,CSm 2 MoO 6 / SPCE电极的检测限低至0.005。μM和2949.72的长线性范围 μM的灵敏度为5.29301 μM.合成的纳米复合材料对枯草芽孢杆菌金黄色葡萄球菌变形杆菌,脆弱拟杆菌大肠杆菌白色念珠菌具有显着的杀菌活性。这些结果使这种绿色催化剂具有用于多种应用的潜力。

更新日期:2021-04-30
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