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Fabrication of high-density and translucent Al-containing garnet, Li7−xLa3Zr2−xTaxO12 (LLZTO) solid-state electrolyte by pressure filtration and sintering
Solid State Ionics ( IF 3.0 ) Pub Date : 2021-04-28 , DOI: 10.1016/j.ssi.2021.115640
Chong Lei , Dinesh K. Shetty , Michael F. Simpson , Anil V. Virkar

Garnet type LLZTO ceramic oxide is a promising solid-state electrolyte for use in Li-ion batteries because it has good chemical stability, adequate mechanical strength. However, lithium dendrite growth still needs to be addressed. The opacity of the solid electrolyte hinders in-situ investigation of dendrite growth. Therefore, semi-transparent LLZTO with high-density is needed. The traditional fabrication process for the garnet type LLZTO is cumbersome, and dense LLZTO disks with high transparency are difficult to fabricate. In this work, Al-LLZTO powder was made by solid-state reaction. A wet ceramic processing method, pressure filtration followed by sintering, was developed to make dense LLZTO with high ionic conductivity (1.47 × 10−4 S/cm) and adequate transmittance (17–23%) to visible light from 500 to 800 nm to observe and monitor dendrite growth.



中文翻译:

通过压力过滤和烧结制备高密度半透明的含铝石榴石,Li 7−x La 3 Zr 2−x Ta x O 12(LLZTO)固态电解质

石榴石型LLZTO陶瓷氧化物是一种有前途的固态电解质,可用于锂离子电池,因为它具有良好的化学稳定性和足够的机械强度。但是,锂枝晶的生长仍然需要解决。固体电解质的不透明性阻碍了枝晶生长的原位研究。因此,需要具有高密度的半透明LLZTO。石榴石型LLZTO的传统制造过程很麻烦,并且难以制造具有高透明度的致密LLZTO光盘。在这项工作中,Al-LLZTO粉末通过固相反应制得。开发了一种湿法陶瓷加工方法,先加压过滤再进行烧结,以制备具有高离子电导率(1.47×10 -4)的致密LLZTO。 S / cm)和对500至800 nm可见光具有足够的透射率(17–23%),以观察和监测树枝状晶体的生长。

更新日期:2021-04-29
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