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International comparison CCQM-K41.2017, hydrogen sulfide in nitrogen
Metrologia ( IF 2.1 ) Pub Date : 2021-03-25 , DOI: 10.1088/0026-1394/58/1a/08010
D Kim 1 , Y Kim 1 , S Lee 1 , J Kang 1 , D Smeulders 2 , H Wu 3 , J Fuko 4 , Janneke I T van Wijk 5 , Adriaan M H van der Veen 5 , J Tshilongo 6 , M Jozela 6 , N Leshabane 6 , G Mphaphuli 6 , N G Ntsasa 6 , F Dias 7 , C Costa 7 , L Konopelko 8 , O Efremova 8 , S Bartlett 9 , P Brewer 9 , A Murugan 9
Affiliation  

Hydrogen sulfide (H2S) is a poisonous gas which can paralyze the respiratory system, quickly leading to death. It is also a flammable gas, which will ignite explosively when exposed to heat, open flames or oxidizers. For these reasons, hydrogen sulfide is classified as a hazardous material. This comparison is a repeat of the key comparison of the "CCQM-K41 (2005)" and it is intended to compare the capabilities of the preparation and value assignment of gas standard of hydrogen sulfide in nitrogen. The range of the nominal amount-of-substance fractions of the comparison standard is 10 mol/mol. A set of hydrogen sulfide in nitrogen gas mixtures were prepared by gravimetry and verified with gas chromatography-atomic emission detector (GC-AED) against a KRISS reference cylinder. The gravimetric values of the amount of substance fractions were adopted as key comparison reference values (KCRVs). The results of 9 participants are consistent with their KCRV. Therefore, it is possible for this key comparison to offer a good traceability and a harmonization among the global distribution data of H2S.

To reach the main text of this paper, click on Final Report. Note that this text is that which appears in Appendix B of the BIPM key comparison database kcdb.bipm.org/.

The final report has been peer-reviewed and approved for publication by the CCQM, according to the provisions of the CIPM Mutual Recognition Arrangement (CIPM MRA).



中文翻译:

国际比较 CCQM-K41.2017,氮气中的硫化氢

硫化氢(H 2S) 是一种有毒气体,可以麻痹呼吸系统,迅速导致死亡。它也是一种易燃气体,遇热、明火或氧化剂会发生爆炸性燃烧。由于这些原因,硫化氢被归类为危险材料。本次比较是对《CCQM-K41(2005)》重点比较的重复,旨在比较氮气中硫化氢气体标准品的制备和赋值能力。比较标准品的标称物质含量范围为 10 mol/mol。通过重量法制备了一组氮气混合物中的硫化氢,并使用气相色谱-原子发射检测器 (GC-AED) 对 KRISS 参考钢瓶进行了验证。采用物质馏分量的重量值作为关键比较参考值(KCRVs)。9 名参与者的结果与他们的 KCRV 一致。因此,这一关键比较有可能在 H 的全球分布数据之间提供良好的可追溯性和协调性。2秒。

要访问本文的正文,请单击最终报告。请注意,此文本出现在 BIPM 密钥比较数据库 kcdb.bipm.org/ 的附录 B 中。

根据 CIPM 互认安排 (CIPM MRA) 的规定,最终报告已通过同行评审并由 CCQM 批准发布。

更新日期:2021-03-25
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