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Sonochemical synthesis of Au/Pd nanoparticles on the surface of LiFePO₄/C cathode material for lithium-ion batteries
Japanese Journal of Applied Physics ( IF 1.5 ) Pub Date : 2021-04-06 , DOI: 10.35848/1347-4065/abeff1
Kotaro Yoshida 1 , Hirokazu Okawa 2 , Yuki Ono 3 , Takahiro Kato 2 , Katsuyasu Sugawara 2
Affiliation  

With the aim of investigating the deposition of Au/Pd core–shell nanoparticles (NPs) on cathode materials to decrease charge transfer resistance, Au/Pd core–shell NPs were successfully synthesized and deposited on LiFePO4 coated with carbon (LiFePO4/C) using ultrasound irradiation. Transmission electron microscopy observation confirmed that dispersed Au/Pd NPs with an average particle size of 7.2nm were deposited on LiFePO4/C. An X-ray diffraction measurement evidenced a peak shifting from 38.2 to 39.1 upon calcination at 400 C in Ar atmosphere, which can be attributed to the phase transition of the Au/Pd NPs from core–shell to alloy.



中文翻译:

锂离子电池LiFePO₄/C正极材料表面Au/Pd纳米颗粒的声化学合成

随着阴极材料调查的Au /钯核-壳纳米颗粒(NP)的沉积,以减少电荷转移电阻的目的,金/钯核-壳纳米颗粒成功地合成和沉积在的LiFePO 4涂覆有碳(的LiFePO 4 / C ) 使用超声波照射。透射电子显微镜观察证实平均粒径为7.2nm的分散的Au/Pd NPs沉积在LiFePO 4 /C上。X 射线衍射测量表明,在 Ar 气氛中在 400 C 下煅烧时,峰从 38.2 移至 39.1,这可归因于 Au/Pd NPs 从核-壳到合金的相变。

更新日期:2021-04-06
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